Crystal and molecular structures of salts of the secondary permethylmetallocenylmethyl cations (C5Me5MC5Me4CHR)+X- (M = Ru, Os; R = Ph, C6F5; X = BF4, PF6)

被引：3

作者：

Kreindlin, AZ ^{[1
]}

Suponitsky, KY ^{[1
]}

Dolgushin, FM ^{[1
]}

Starikova, ZA ^{[1
]}

Rybinskaya, MI ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2001年 / 50卷 / 09期

关键词：

ruthenium; osmium; permethylmetallocenylmethyl cations; X-ray diffraction analysis; NMR spectroscopy;

D O I：

10.1023/A:1013038602864

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structures of tetrafluoroborates of the secondary permethylmetallocenylmethyl cations [Cp*MC5Me4CHR](+) (Cp* = C5Me5; 1b; M = Ru Ph; 1e: M = Os, R = C6F5) were established by X-ray diffraction analysis. The angles of inclination (alpha) of the C(1)-C(11) bond coordinated to the metal atom with respect to the plane of the C5Me4 ligand are 31.5degrees and 35.6degrees, and the M-C(11) distances are 2.506 and 2.401 Angstrom in 1b,c, respectively.

引用

页码：1616 / 1619

页数：4

共 50 条

[1] Crystal and molecular structures of salts of the secondary permethylmetallocenylmethyl cations (C5Me5MC5Me4CHR)+X– (M = Ru, Os; R = Ph, C6F5; X = BF4, PF6)
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K. Yu. Suponitsky
F. M. Dolgushin
Z. A. Starikova
M. I. Rybinskaya
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[2] Iron- and ruthenium-containing triple-decker complexes with a central pentaphospholyl ligand -: X-ray structures of [(η-C5H5)Fe(μ-η:η-P5)Ru(η-C5Me5)]PF6 and [(η-C5Me5)Ru(μ-η:η-P5)Ru(η-C5Me5)]PF6
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[6] Synthesis, structure and reactivities of the dinuclear μ-η1:η6-arylethynyl ruthenium complexes [Cp(PR3)2Ru(μ-η1:η6-C≡CC6H4Me-p)RuCp*]•Cl (R = Ph, Me; Cp = η5-C5H5, Cp* = η5-C5Me5).: The molecular structure of [Cp(PPh3)2Ru(μ-η1:η6-C≡CC6H4Me-p)RuCp*]•PF6
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[7] [(C6F5)2IF2][BF4], the first salt with the electrophilic cation [(C6F5)2IF2]+:: Synthesis, reactivity, and structure
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[9] Synthesis and characterization of [(Cp*)Ru(PPh3)(N-base)]X and [η5-C9H7)Ru(PPh3)(N-base)]X complexes:: crystal and molecular structure of the complex [(η5-C9H7)Ru(PPh3)(phen)]PF6 (CP* = C5Me5, indenyl = C9H7; N-bases = bipy and phen; X = BF4 or PF6)
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[10] The preparation of mixed ligand ruthenocenes containing bulky cyclopentadienyl ligands.: Crystal structures of pentaphenylruthenocene, [Ru(η5-C5Ph5)(η5-C5H5)], pentaparatolylruthenocene, [Ru{η5-C5(p-MeC6H4)5}(η5-C5H5)] and pentaphenylpentamethylruthenocene, [Ru(η5-C5Ph5)(η5-C5Me5)]
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