Laccase-a natural source for the synthesis of benzofuro[2,3-c]pyrazolin-5-ones

被引：10

作者：

Kidwai, Mazaahir ^{[1
]}

Jain, Arti ^{[1
]}

Sharma, Abha ^{[2
]}

Kuhad, Ramesh Chander ^{[2
]}

机构：

[1] Univ Delhi, Dept Chem, Green Chem Res Lab, Delhi 110007, India

[2] Univ Delhi, Dept Microbiol, Lignocellulose Biotechnol Lab, New Delhi 110021, India

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2013年 / 3卷 / 01期

关键词：

DERIVATIVES; TYROSINASE; INHIBITORS; REDUCTION; BINDING; WATER;

D O I：

10.1039/c2cy20452e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Enzymatic oxidation of catechols/hydroquinones in the presence of pyrazolin-5-ones as a nucleophile in aqueous solution has been investigated in detail by applying laccase as a catalyst. This is the first report for the enzymatic synthesis of a novel series of compounds. We derived some new compounds with the catechol/hydroquinone ring in moderate yields based on enzymatic synthesis in an environmentally benign aqueous solution. These types of reactions represent a milestone along the path of future sustainable green chemistry.

引用

页码：230 / 234

页数：5

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