A novel route for preparing graphitic ordered mesoporous carbon as electrochemical energy storage material

被引:37
作者
Yuan, Dingsheng [1 ]
Zeng, Fulong [1 ]
Yan, Jin [1 ]
Yuan, Xiaoli [1 ]
Huang, Xiangjin [1 ]
Zou, Wujun [1 ]
机构
[1] Jinan Univ, Dept Chem, Guangzhou 510632, Guangdong, Peoples R China
来源
RSC ADVANCES | 2013年 / 3卷 / 16期
基金
中国国家自然科学基金;
关键词
NITROGEN-DOPED GRAPHENE; CATALYTIC GRAPHITIZATION; METHANOL ELECTROOXIDATION; NANOPOROUS CARBON; CRYSTALLINE WALLS; SILICA; NANOPARTICLES; TEMPLATE; SUCROSE; OXIDE;
D O I
10.1039/c3ra40677f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A graphitic ordered mesoporous carbon (G-OMC) has been synthesized for the first time using mesoporous nickel oxide as a template and catalyst and dopamine as a carbon source. The probable formation mechanism for the preparation of G-OMC is also proposed. Characterization by X-ray diffraction, Raman spectroscopy and high resolution transmission electron microscopy indicate that the as-prepared mesoporous carbon has a high degree of graphitization. The electrochemical performance of G-OMC is visibly superior to typical CMK-3D in alkalic media, involving fast kinetic transfer, anti-corrosion, a capacitance of 68 mu F cm(-2) at 0.1 A g(-1) and a light increase of the 6000th-cycle capacitance compared to the initial capacitance. In organic electrolyte, a wider potential window of 2.5 V is presented. The fast charge transfer, quick response and anti-corrosion properties promise that G-OMC will have a great prospect as a supercapacitor for energy storage applications.
引用
收藏
页码:5570 / 5576
页数:7
相关论文
共 45 条
  • [1] Catalytic graphitization of an amorphous carbon film under focused electron beam irradiation due to the presence of sputtered nickel metal particles
    Aikawa, Shinya
    Kizu, Takio
    Nishikawa, Eiichi
    [J]. CARBON, 2010, 48 (10) : 2997 - 2999
  • [2] Honeycomb Carbon: A Review of Graphene
    Allen, Matthew J.
    Tung, Vincent C.
    Kaner, Richard B.
    [J]. CHEMICAL REVIEWS, 2010, 110 (01) : 132 - 145
  • [3] Carbon-based electronics
    Avouris, Phaedon
    Chen, Zhihong
    Perebeinos, Vasili
    [J]. NATURE NANOTECHNOLOGY, 2007, 2 (10) : 605 - 615
  • [4] "Brick-and-Mortar" Self-Assembly Approach to Graphitic Mesoporous Carbon Nanocomposites
    Fulvio, Pasquale F.
    Mayes, Richard T.
    Wang, Xiqing
    Mahurin, Shannon M.
    Bauer, John C.
    Presser, Volker
    McDonough, John
    Gogotsi, Yury
    Dai, Sheng
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (12) : 2208 - 2215
  • [5] Synthesis of Partially Graphitic Ordered Mesoporous Carbons with High Surface Areas
    Gao, Wenjun
    Wan, Ying
    Dou, Yuqian
    Zhao, Dongyuan
    [J]. ADVANCED ENERGY MATERIALS, 2011, 1 (01) : 115 - 123
  • [6] Real-time observation of tubule formation from amorphous carbon nanowires under high-bias Joule heating
    Huang, J. Y.
    Chen, S.
    Ren, Z. F.
    Chen, G.
    Dresselhaus, M. S.
    [J]. NANO LETTERS, 2006, 6 (08) : 1699 - 1705
  • [7] Pure ionic liquid electrolytes compatible with a graphitized carbon negative electrode in rechargeable lithium-ion batteries
    Ishikawa, Masashi
    Sugimoto, Toshinori
    Kikuta, Manabu
    Ishiko, Eriko
    Kono, Michiyuki
    [J]. JOURNAL OF POWER SOURCES, 2006, 162 (01) : 658 - 662
  • [8] Nitrogen-Doped Graphene for High-Performance Ultracapacitors and the Importance of Nitrogen-Doped Sites at Basal Planes
    Jeong, Hyung Mo
    Lee, Jung Woo
    Shin, Weon Ho
    Choi, Yoon Jeong
    Shin, Hyun Joon
    Kang, Jeung Ku
    Choi, Jang Wook
    [J]. NANO LETTERS, 2011, 11 (06) : 2472 - 2477
  • [9] Ordered mesoporous Fe2O3 with crystalline walls
    Jiao, F
    Harrison, A
    Jumas, JC
    Chadwick, AV
    Kockelmann, W
    Bruce, PG
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (16) : 5468 - 5474
  • [10] Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles
    Joo, SH
    Choi, SJ
    Oh, I
    Kwak, J
    Liu, Z
    Terasaki, O
    Ryoo, R
    [J]. NATURE, 2001, 412 (6843) : 169 - 172