15N NMR of 1,4-dihydropyridine derivatives

被引：2

作者：

Goba, Inguna ^{[1
]}

Liepinsh, Edvards ^{[1
]}

机构：

[1] Latvian Inst Organ Synth, LV-1006 Riga, Latvia

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 2013年 / 51卷 / 07期

关键词：

NMR; 15N NMR chemical shifts; 1HN NMR chemical shifts; 1J(15N-1H) coupling constants; substituent effect; solvent effect; quantum chemical calculations; 1; 4-DHP; SPIN COUPLING-CONSTANTS; CONFORMATIONAL-ANALYSIS; C-13; H-1; ANTAGONISTS; ASSIGNMENT; MECHANISM; N-15; BOND;

D O I：

10.1002/mrc.3959

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this article, we describe the characteristic 15N and 1HN NMR chemical shifts and 1J(15N-1H) coupling constants of various symmetrically and unsymmetrically substituted 1,4-dihydropyridine derivatives. The NMR chemical shifts and coupling constants are discussed in terms of their relationship to structural features such as character and position of the substituent in heterocycle, N-alkyl substitution, nitrogen lone pair delocalization within the conjugated system, and steric effects. Copyright (c) 2013 John Wiley & Sons, Ltd.

引用

页码：391 / 396

页数：6

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