Synthesis of tremella-like CoS and its application in sensing of hydrogen peroxide and glucose

被引:56
作者
Wu, Wenqin [1 ]
Yu, Beibei [1 ]
Wu, Huimin [1 ]
Wang, Shengfu [1 ]
Xia, Qinghua [1 ]
Ding, Yu [2 ]
机构
[1] Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Key Lab Synth & Applicat Organ Funct Mol, Minist Educ,Coll Chem & Chem Engn, Wuhan 430062, Peoples R China
[2] Hubei Engn Univ, Coll Chem & Mat Sci, Xiaogan 432000, Peoples R China
来源
MATERIALS SCIENCE AND ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS | 2017年 / 70卷
基金
中国国家自然科学基金;
关键词
Electrocatalysis; Tremella-like CoS; Non-enzymatic hydrogen peroxide sensor; Glucose sensor; NONENZYMATIC ELECTROCHEMICAL SENSORS; CARBON-PASTE ELECTRODE; FACILE FABRICATION; COBALT SULFIDE; AMPEROMETRIC BIOSENSOR; NANOPOROUS PLATINUM; URIC-ACID; THIN-FILM; GRAPHENE; NANOPARTICLES;
D O I
10.1016/j.msec.2016.08.084
中图分类号
TB3 [工程材料学]; R318.08 [生物材料学];
学科分类号
0805 ; 080501 ; 080502 ;
摘要
Different phases of cobalt sulfides have been fabricated by one-pot hydrothermal method. Comparing all of the prepared materials, and the results revealed that CoS was the most conductive and could accelerate electron transfer. The CoS presented tremella-like and excellent catalytic activities towards hydrogen peroxide and glucose. The sensor based on CoS performed amperometric sensing of hydrogen peroxide in a linear range between 5.00 mu M and 14.82 mM. Meanwhile, sensing of glucose with double-linear range, one is between 5.00 NM and 1.10 mM, the other is between 1.20 mM and 10.20 mM. These due to the fact that more and more intermediate species absorb onto electrode surface with increasing the concentration of glucose, which limit the following glucose oxidation. Furthermore, the hydrogen peroxide and glucose sensors based on tremella-like CoS also exhibited excellent selectivity, stability, and reproducibility. Thus, the sensor showed potential utilities in hydrogen peroxide and glucose detection. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:430 / 437
页数:8
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