Identification of isomers in the gas phase and as adsorbates by near-edge X-ray absorption fine structure spectroscopy: Cis- and trans-stilbene

被引：6

作者：

Puettner, Ralph ^{[1
]}

Schmidt-Weber, Philipp ^{[2
,5
]}

Kampen, Thorsten ^{[3
]}

Kolczewski, Christine ^{[4
]}

Hermann, Klaus ^{[2
]}

Horn, Karsten ^{[2
]}

机构：

[1] Free Univ Berlin, Dept Phys, D-14195 Berlin, Germany

[2] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany

[3] SPECS Surface Nano Anal GmbH, D-13355 Berlin, Germany

[4] Deutsch Museum Munchen, D-80538 Munich, Germany

[5] TDK Stahnsdorf, Stahnsdorf, Germany

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 2017年 / 215卷

关键词：

ELECTRONIC-SPECTRUM; ETHYLENE ADSORPTION; SI(100)2 X-1; MOLECULES;

D O I：

10.1016/j.elspec.2016.11.014

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Near-edge x-ray absorption fine structure spectra of the cis- and trans-isomers of stilbene in the gas phase reveal clear differences, which are analyzed by results from density-functional theory calculations using the transition potential approach. The differences between the two species also occur in stilbene adsorbed on Si(100), opening the way towards studying structural changes in molecules in different surface environments, and configurational switching in organic molecules on surfaces in particular. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：16 / 21

页数：6

共 26 条

[1] Fingerprint IR spectroscopy to probe amino acid conformations in the gas phase [J].

Bakker, JM ;

Aleese, LM ;

Meijer, G ;

von Helden, G .

PHYSICAL REVIEW LETTERS, 2003, 91 (20)

[2]

BENFERINGA L, 2001, MOL SWITCHES

[3] A high resolution photoemission study of phenol adsorption on Si(100)2 x 1 [J].

Casaletto, MP ;

Carbone, M ;

Piancastelli, MN ;

Horn, K ;

Weiss, K ;

Zanoni, R .

SURFACE SCIENCE, 2005, 582 (1-3) :42-48

[4] Ethylene adsorption on Si(100)2X1: A high-resolution photoemission study [J].

Casaletto, MP ;

Zanoni, R ;

Carbone, M ;

Piancastelli, MN ;

Aballe, L ;

Weiss, K ;

Horn, K .

PHYSICAL REVIEW B, 2000, 62 (24) :17128-17133

[5] The surface as molecular reagent: organic chemistry at the semiconductor interface [J].

Filler, MA ;

Bent, SF .

PROGRESS IN SURFACE SCIENCE, 2003, 73 (1-3) :1-56

[6]

Fink A., 2001, PHYS REV B, V67

[7] Nanoscale science of single molecules using local probes [J].

Gimzewski, JK ;

Joachim, C .

SCIENCE, 1999, 283 (5408) :1683-1688

[8]

Hermann K., STOBE SOFTWARE

[9] INNER-SHELL EXCITATION OF FORMALDEHYDE, ACETALDEHYDE AND ACETONE STUDIED BY ELECTRON-IMPACT [J].

HITCHCOCK, AP ;

BRION, CE .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1980, 19 (03) :231-250

[10] Thermal decomposition of ethylene on Si(111):: Formation of the Si(111)√3 x √3:: carbon structure [J].

Kim, J. W. ;

Kampen, T. U. ;

Horn, K. ;

Jung, M. C. .

SURFACE SCIENCE, 2007, 601 (03) :694-698

← 1 2 3 →