Green Organocatalytic Oxidation of Sulfides to Sulfoxides and Sulfones

被引：64
|
作者：
Voutyritsa, Errika [1 ]
Triandafillidi, Ierasia [1 ]
Kokotos, Christoforos G. [1 ]
机构：
[1] Univ Athens, Organ Chem Lab, Dept Chem, Athens 15771, Greece
来源：
SYNTHESIS-STUTTGART | 2017年 / 49卷 / 04期
关键词：
organocatalytic oxidation; sulfoxides; fulsones; hydrogen peroxide; green chemistry; AQUEOUS HYDROGEN-PEROXIDE; ONE-POT SYNTHESIS; SELECTIVE OXIDATION; IONIC LIQUIDS; ASYMMETRIC OXIDATION; CATALYZED OXIDATION; ORGANIC SULFIDES; MILD OXIDATION; DESULFURIZATION; EFFICIENT;
D O I：
10.1055/s-0036-1588315
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A highly efficient synthetic methodology towards the selective synthesis of sulfaxides and sulf nes is reported using a cheap and reen organocatalytic method. Starting from sulfides and using 2,2,2-trifluoroacetophenone as the organocatalyst and H2O2 as the oxidant, the high-yielding preparation of sulfoxides or sulfones is described, lie ing dependent on the reaction conditions
引用
收藏
页码：917 / 924
页数：8
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