Green Organocatalytic Oxidation of Sulfides to Sulfoxides and Sulfones

被引：67

作者：

Voutyritsa, Errika ^{[1
]}

Triandafillidi, Ierasia ^{[1
]}

Kokotos, Christoforos G. ^{[1
]}

机构：

[1] Univ Athens, Organ Chem Lab, Dept Chem, Athens 15771, Greece

来源：

SYNTHESIS-STUTTGART | 2017年 / 49卷 / 04期

关键词：

organocatalytic oxidation; sulfoxides; fulsones; hydrogen peroxide; green chemistry; AQUEOUS HYDROGEN-PEROXIDE; ONE-POT SYNTHESIS; SELECTIVE OXIDATION; IONIC LIQUIDS; ASYMMETRIC OXIDATION; CATALYZED OXIDATION; ORGANIC SULFIDES; MILD OXIDATION; DESULFURIZATION; EFFICIENT;

D O I：

10.1055/s-0036-1588315

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly efficient synthetic methodology towards the selective synthesis of sulfaxides and sulf nes is reported using a cheap and reen organocatalytic method. Starting from sulfides and using 2,2,2-trifluoroacetophenone as the organocatalyst and H2O2 as the oxidant, the high-yielding preparation of sulfoxides or sulfones is described, lie ing dependent on the reaction conditions

引用

页码：917 / 924

页数：8

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