Research Progress in Preparation and Purification of Rare Earth Metals

被引:38
作者
Liu, Hang [1 ]
Zhang, Yao [2 ]
Luan, Yikun [1 ]
Yu, Huimin [3 ]
Li, Dianzhong [1 ]
机构
[1] Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China
[2] Chinese Acad Sci, Baotou Rare Earth R&D Ctr, Baotou 014000, Peoples R China
[3] Northeastern Univ, Sch Met, Shenyang 110819, Peoples R China
关键词
rare earth metals; purity; impurity concentration; preparation; purification; RE-O RE=GD; IMPURITY DISTRIBUTION; GADOLINIUM; TERBIUM; SILICON; OXYGEN; NANOWIRES; DIFFUSION; EMISSION; ELEMENTS;
D O I
10.3390/met10101376
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The purity of rare earth metals is one of the most important factors to research and develop high technique materials. However, high purity rare earth metals are not easily achieved. This review summarizes the preparation and purification methods of rare earth metals. First, the preparation principle and process of molten salt electrolysis and metal thermal reduction are introduced. The main sources of metallic impurities and interstitial impurities in rare earth metals as well as the action mechanism of reducing the concentration of different impurities are analyzed and summarized. Then, the purification principle and process of vacuum distillation, arc melting, zone melting, and solid state electromigration are also discussed. Furthermore, the removal effect and function rule of metallic impurities and interstitial impurities in rare earth metals are outlined. Finally, the crucial issues in the development of high purity rare earth metals are put forward, and the development direction of high purity rare earth metals in future are pointed out on this basis.
引用
收藏
页码:1 / 13
页数:13
相关论文
共 84 条
  • [1] Structural, magnetic and magnetocaloric properties of La0.5Sm0.2Sr0.3Mn1-xFexO3 compounds with (0 ≤ x ≤ 0.15)
    Abdouli, Kh
    Cherif, W.
    Omrani, H.
    Mansouri, M.
    Valent, M. A.
    Graca, M. P. F.
    Ktari, L.
    [J]. JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2019, 475 : 635 - 642
  • [2] Arwin G., 2015, THESIS
  • [3] PURIFICATION OF EUROPIUM
    BUSCH, G
    KALDIS, E
    MUHEIM, J
    BISCHOF, R
    [J]. JOURNAL OF THE LESS-COMMON METALS, 1971, 24 (04): : 453 - &
  • [4] Estimating perfluorocarbon emission factors for industrial rare earth metal electrolysis
    Cai, Bofeng
    Liu, Helin
    Kou, Fan
    Yang, Youming
    Yao, Bo
    Chen, Xiping
    Wong, David S.
    Zhang, Lizhi
    Li, Jianzhong
    Kuang, Guochun
    Chen, Liqu
    Zheng, Jinwen
    Guan, Dabo
    Shan, Yuli
    [J]. RESOURCES CONSERVATION AND RECYCLING, 2018, 136 : 315 - 323
  • [5] Chen G.H., 2015, RARE EARTH INF, V379, P15
  • [6] [陈国华 Chen Guohua], 2015, [中国稀土学报, Journal of the Chinese Society of Rare Earths], V33, P206
  • [7] [陈宇昕 Chen Yuxin], 2014, [稀土, Chinese Rare Earths], V35, P99
  • [8] [成维 Cheng Wei], 2013, [矿冶工程, Mining and Metallurgical Engineering], V33, P104
  • [9] Electrorecrystallization of Metal Alloy
    Chiu, Ying-Ta
    Lin, Kwang-Lung
    Wu, Albert T.
    Jang, Wei-Luen
    Dong, Chung-Li
    Lai, Yi-Shao
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 549 : 190 - 194
  • [10] Current progress and future challenges in rare-earth-free permanent magnets
    Cui, Jun
    Kramer, Matthew
    Zhou, Lin
    Liu, Fei
    Gabay, Alexander
    Hadjipanayis, George
    Balasubramanian, Balamurugan
    Sellmyer, David
    [J]. ACTA MATERIALIA, 2018, 158 : 118 - 137