Vibrational, electrical, and structural properties of PVDF-LiBOB solid polymer electrolyte with high electrochemical potential window

被引:28
作者
Chowdhury, Faisal I. [1 ,2 ]
Khandaker, M. U. [3 ]
Amin, Y. M. [3 ]
Kufian, M. Z. [1 ]
Woo, H. J. [1 ]
机构
[1] Univ Malaya, Dept Phys, Ctr Ion, Kuala Lumpur 50603, Malaysia
[2] Univ Chittagong, Dept Chem, Chittagong 4331, Bangladesh
[3] Univ Malaya, Dept Phys, Appl Radiat Lab, Fac Sci, Kuala Lumpur 50603, Malaysia
关键词
Polyvinylidene difluoride; Lithium bis(oxalato)borate; Solid polymer electrolyte; Conductivity; Vibrational studies; THERMAL-STABILITY; LITHIUM; TEMPERATURE; GRAPHITE; PERFORMANCE; BATTERIES; EC/DEC; LIPF6; SALT;
D O I
10.1007/s11581-016-1857-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Polyvinylidene difluoride (PVDF)-lithium bis(oxalato)borate (LiBOB) solid polymer electrolytes (SPEs) have been prepared by solution casting. The highest ionic conductivity achieved is 3.4610(-3) S cm(-1). Electrochemical potential window of the SPEs is found around 4.7 V. Interaction between PVDF and LiBOB is studied systematically. The changes of C-C, CF2, and CH2 vibration modes with an emerging shoulder are analyzed. At higher salt content, this shoulder becomes more prominent peak at the expense of CF2 vibration mode. This suggests the possible Li+center dot center dot center dot F coordination. Deconvolution of IR spectra region from 1750 to 1850 cm(-1) has been carried out to estimate the relative percentage of free ions and contact ions. The finding is in good agreement with conductivity and XRD results. When more salt is present, the number of free ions percentage increases and the Full width at half-maximum (FWHM) of (110) plane is broadening. The Li+center dot center dot center dot F interaction breaks the folding patterns of polymer chain and enhances amorphousness domain.
引用
收藏
页码:275 / 284
页数:10
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