Thermal Methane Activation by a Binary V-Nb Transition-Metal Oxide Cluster Cation: A Further Example for the Crucial Role of Oxygen-Centered Radicals

被引：27
作者：
Wang, Zhe-Chen [1 ,3 ]
Liu, Jian-Wen [2 ,4 ]
Schlangen, Maria [1 ]
Weiske, Thomas [1 ]
Schroeder, Detlef [5 ]
Sauer, Joachim [2 ]
Schwarz, Helmut [1 ]
机构：
[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
[2] Humboldt Univ, Inst Chem, D-10099 Berlin, Germany
[3] Colorado State Univ, Dept Chem, Ft Collins, CO 80526 USA
[4] Natl Supercomp Ctr Shenzhen, Shenzhen 518055, Peoples R China
[5] Acad Sci Czech Republic, Inst Organ Chem & Biochem, CR-16610 Prague 6, Czech Republic
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 35期
关键词：
binary oxide cluster; density functional calculations; mass spectrometry; methane activation; radical ions; HYDROGEN-ATOM ABSTRACTION; GAS-PHASE REACTIONS; ZETA VALENCE QUALITY; H BOND ACTIVATION; C-H; ROOM-TEMPERATURE; BASIS-SETS; MOLECULAR-OXYGEN; BARE FEO+; IONS;
D O I：
10.1002/chem.201302133
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The heteronuclear transition-metal oxide cluster activates methane: VNbO5+ reacts with CH4 under ambient conditions via hydrogen-atom transfer (HAT), thus providing an interesting prototype example of room-temperature methane activation by a binary transition-metal oxide cluster. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：11496 / 11501
页数：6
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