Thermal Methane Activation by a Binary V-Nb Transition-Metal Oxide Cluster Cation: A Further Example for the Crucial Role of Oxygen-Centered Radicals

被引：27

作者：

Wang, Zhe-Chen ^{[1
,3
]}

Liu, Jian-Wen ^{[2
,4
]}

Schlangen, Maria ^{[1
]}

Weiske, Thomas ^{[1
]}

Schroeder, Detlef ^{[5
]}

Sauer, Joachim ^{[2
]}

Schwarz, Helmut ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany

[2] Humboldt Univ, Inst Chem, D-10099 Berlin, Germany

[3] Colorado State Univ, Dept Chem, Ft Collins, CO 80526 USA

[4] Natl Supercomp Ctr Shenzhen, Shenzhen 518055, Peoples R China

[5] Acad Sci Czech Republic, Inst Organ Chem & Biochem, CR-16610 Prague 6, Czech Republic

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 35期

关键词：

binary oxide cluster; density functional calculations; mass spectrometry; methane activation; radical ions; HYDROGEN-ATOM ABSTRACTION; GAS-PHASE REACTIONS; ZETA VALENCE QUALITY; H BOND ACTIVATION; C-H; ROOM-TEMPERATURE; BASIS-SETS; MOLECULAR-OXYGEN; BARE FEO+; IONS;

D O I：

10.1002/chem.201302133

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The heteronuclear transition-metal oxide cluster activates methane: VNbO5+ reacts with CH4 under ambient conditions via hydrogen-atom transfer (HAT), thus providing an interesting prototype example of room-temperature methane activation by a binary transition-metal oxide cluster. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11496 / 11501

页数：6

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