Organocatalytic conversion of cellulose into a platform chemical
被引:74
作者:
Caes, Benjamin R.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Dept Chem, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
Caes, Benjamin R.
[1
]
Palte, Michael J.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Med Scientist Training Program, Madison, WI 53706 USA
Univ Wisconsin, Mol & Cellular Pharmacol Grad Training Program, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
Palte, Michael J.
[2
,3
]
Raines, Ronald T.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Dept Chem, Madison, WI 53706 USA
Univ Wisconsin, Dept Biochem, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
Raines, Ronald T.
[1
,4
]
机构:
[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA
[2] Univ Wisconsin, Med Scientist Training Program, Madison, WI 53706 USA
[3] Univ Wisconsin, Mol & Cellular Pharmacol Grad Training Program, Madison, WI 53706 USA
[4] Univ Wisconsin, Dept Biochem, Madison, WI 53706 USA
The search for a source of fuels and chemicals that is both abundant and renewable has become of paramount importance. The polysaccharide cellulose meets both criteria, and methods have been developed for its transformation into the platform chemical 5-(hydroxymethyl)furfural (HMF). These methods typically employ harsh reaction conditions or toxic heavy metal catalysts, deterring large-scale implementation. Here, we describe a low-temperature, one-pot route that uses ortho-carboxyl-substituted phenylboronic acids as organocatalysts in conjunction with hydrated magnesium chloride and mineral acids to convert cellulose and cellulose-rich municipal waste to HMF in yields comparable to processes that use toxic heavy metal catalysts. Isotopic labeling studies indicate that the key aldose-to-ketose transformation occurs via an enediol intermediate. The route, which also allows for facile catalyst recovery and recycling, provides a green prototype for cellulose conversion.
机构:
Univ Wisconsin, Dept Chem, Madison, WI 53706 USA
Univ Calif Berkeley, Energy Biosci Inst, Berkeley, CA 94720 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
Binder, Joseph B.
Blank, Jacqueline J.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Dept Biochem, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
Blank, Jacqueline J.
Cefali, Anthony V.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Coll Agr & Life Sci, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
Cefali, Anthony V.
Raines, Ronald T.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Dept Chem, Madison, WI 53706 USA
Univ Wisconsin, Dept Biochem, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
机构:
Univ Wisconsin, Dept Chem, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
Binder, Joseph B.
Cefali, Anthony V.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Coll Agr & Life Sci, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
Cefali, Anthony V.
Blank, Jacqueline J.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Dept Biochem, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
Blank, Jacqueline J.
Raines, Ronald T.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Dept Chem, Madison, WI 53706 USA
Univ Wisconsin, Dept Biochem, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
机构:
Univ Wisconsin, Dept Chem, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
Binder, Joseph B.
Raines, Ronald T.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Dept Chem, Madison, WI 53706 USA
Univ Wisconsin, Dept Biochem, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
机构:
Univ Birmingham, Birmingham B15 2TT, W Midlands, EnglandUniv Birmingham, Birmingham B15 2TT, W Midlands, England
Daniel, Ritchie
Tian, Guohong
论文数: 0引用数: 0
h-index: 0
机构:
Univ Birmingham, Birmingham B15 2TT, W Midlands, England
Newcastle Univ, Sir Joseph Swan Ctr, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, EnglandUniv Birmingham, Birmingham B15 2TT, W Midlands, England
Tian, Guohong
Xu, Hongming
论文数: 0引用数: 0
h-index: 0
机构:
Univ Birmingham, Birmingham B15 2TT, W Midlands, EnglandUniv Birmingham, Birmingham B15 2TT, W Midlands, England
Xu, Hongming
Wyszynski, Miroslaw L.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Birmingham, Birmingham B15 2TT, W Midlands, EnglandUniv Birmingham, Birmingham B15 2TT, W Midlands, England
Wyszynski, Miroslaw L.
Wu, Xuesong
论文数: 0引用数: 0
h-index: 0
机构:
Univ Birmingham, Birmingham B15 2TT, W Midlands, England
Xi An Jiao Tong Univ, State Key Lab Multiphase Flow Power Engn, Xian 710049, Peoples R ChinaUniv Birmingham, Birmingham B15 2TT, W Midlands, England
Wu, Xuesong
Huang, Zuohua
论文数: 0引用数: 0
h-index: 0
机构:
Xi An Jiao Tong Univ, State Key Lab Multiphase Flow Power Engn, Xian 710049, Peoples R ChinaUniv Birmingham, Birmingham B15 2TT, W Midlands, England
机构:
Univ Wisconsin, Dept Biochem, Madison, WI 53706 USAUniv Wisconsin, Dept Biochem, Madison, WI 53706 USA
Ellis, Gregory A.
Palte, Michael J.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Med Scientist Training Program, Madison, WI 53706 USA
Univ Wisconsin, Mol & Cellular Pharmacol Grad Training Program, Madison, WI 53706 USAUniv Wisconsin, Dept Biochem, Madison, WI 53706 USA
Palte, Michael J.
Raines, Ronald T.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Dept Biochem, Madison, WI 53706 USA
Univ Wisconsin, Dept Chem, Madison, WI 53706 USAUniv Wisconsin, Dept Biochem, Madison, WI 53706 USA
机构:
Univ Wisconsin, Dept Chem, Madison, WI 53706 USA
Univ Calif Berkeley, Energy Biosci Inst, Berkeley, CA 94720 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
Binder, Joseph B.
Blank, Jacqueline J.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Dept Biochem, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
Blank, Jacqueline J.
Cefali, Anthony V.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Coll Agr & Life Sci, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
Cefali, Anthony V.
Raines, Ronald T.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Dept Chem, Madison, WI 53706 USA
Univ Wisconsin, Dept Biochem, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
机构:
Univ Wisconsin, Dept Chem, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
Binder, Joseph B.
Cefali, Anthony V.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Coll Agr & Life Sci, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
Cefali, Anthony V.
Blank, Jacqueline J.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Dept Biochem, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
Blank, Jacqueline J.
Raines, Ronald T.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Dept Chem, Madison, WI 53706 USA
Univ Wisconsin, Dept Biochem, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
机构:
Univ Wisconsin, Dept Chem, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
Binder, Joseph B.
Raines, Ronald T.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Dept Chem, Madison, WI 53706 USA
Univ Wisconsin, Dept Biochem, Madison, WI 53706 USAUniv Wisconsin, Dept Chem, Madison, WI 53706 USA
机构:
Univ Birmingham, Birmingham B15 2TT, W Midlands, EnglandUniv Birmingham, Birmingham B15 2TT, W Midlands, England
Daniel, Ritchie
Tian, Guohong
论文数: 0引用数: 0
h-index: 0
机构:
Univ Birmingham, Birmingham B15 2TT, W Midlands, England
Newcastle Univ, Sir Joseph Swan Ctr, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, EnglandUniv Birmingham, Birmingham B15 2TT, W Midlands, England
Tian, Guohong
Xu, Hongming
论文数: 0引用数: 0
h-index: 0
机构:
Univ Birmingham, Birmingham B15 2TT, W Midlands, EnglandUniv Birmingham, Birmingham B15 2TT, W Midlands, England
Xu, Hongming
Wyszynski, Miroslaw L.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Birmingham, Birmingham B15 2TT, W Midlands, EnglandUniv Birmingham, Birmingham B15 2TT, W Midlands, England
Wyszynski, Miroslaw L.
Wu, Xuesong
论文数: 0引用数: 0
h-index: 0
机构:
Univ Birmingham, Birmingham B15 2TT, W Midlands, England
Xi An Jiao Tong Univ, State Key Lab Multiphase Flow Power Engn, Xian 710049, Peoples R ChinaUniv Birmingham, Birmingham B15 2TT, W Midlands, England
Wu, Xuesong
Huang, Zuohua
论文数: 0引用数: 0
h-index: 0
机构:
Xi An Jiao Tong Univ, State Key Lab Multiphase Flow Power Engn, Xian 710049, Peoples R ChinaUniv Birmingham, Birmingham B15 2TT, W Midlands, England
机构:
Univ Wisconsin, Dept Biochem, Madison, WI 53706 USAUniv Wisconsin, Dept Biochem, Madison, WI 53706 USA
Ellis, Gregory A.
Palte, Michael J.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Med Scientist Training Program, Madison, WI 53706 USA
Univ Wisconsin, Mol & Cellular Pharmacol Grad Training Program, Madison, WI 53706 USAUniv Wisconsin, Dept Biochem, Madison, WI 53706 USA
Palte, Michael J.
Raines, Ronald T.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Wisconsin, Dept Biochem, Madison, WI 53706 USA
Univ Wisconsin, Dept Chem, Madison, WI 53706 USAUniv Wisconsin, Dept Biochem, Madison, WI 53706 USA