Development of Dispersed-Catalyst/NSTF Hybrid Electrode

Ultrathin electrodes, such as the 3M Nanostructured Thin Film (NSTF) electrode, provide a plausible pathway to reduce platinum cost in low temperature fuel cells. However, several operational shortcomings, involving relatively poor electrode proton conduction and tendencies to collect water in the cathode, were observed in our fuel cell tests. This can be greatly mitigated when a few-micron thick dispersed-catalyst layer is placed adjacent to the NSTF layer, forming a dispersed-catalyst/NSTF hybrid electrode. This dispersed-catalyst layer is also called the "interlayer" because it is located between the NSTF layer and the microporous layer of the cathode diffusion medium. In this study, development of the hybrid electrode was pursued. Emphasis on developing lab-scale fabrication methods that can easily translate to roll-to-roll manufacturing process was a key element of the hybrid electrode development. The fuel cell performance of the electrode showed high sensitivity to fabrication methods. When the dispersed-catalyst layer was coated directly on the NSTF electrode, voltage at high current density dropped significantly. The voltage loss was surmised to be caused by ionomer seepage into the NSTF layer during the coating process. This voltage loss could be eliminated by placing the dispersed-catalyst layer on the gas-diffusion layer and then located adjacent to the NSTF cathode. Interaction between the dispersed-catalyst and NSTF layers and how it affects the fuel cell performance is discussed. (C) 2012 The Electrochemical Society. [DOI: 10.1149/2.023211jes] All rights reserved.