Ordered nanostructures from the self-assembly of reactive coil-rod-coil molecules

被引：42
作者：
Jin, LY
Bae, J
Ryu, JH
Lee, M
机构：
[1] Yonsei Univ, Ctr Supramol Nanoassembly, Seoul 120749, South Korea
[2] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
[3] Yanbian Univ, Coll Sci & Engn, Dept Chem, Yanji 133002, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 04期
关键词：
liquid crystals; nanotechnology; polymers; supramolecular chemistry; Suzuki coupling;
D O I：
10.1002/anie.200502911
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Keeping in shape: Polymerizable coil-rod-coil molecules self-organize into 2D columnar and 3D bicontinuous liquid crystals whose supramolecular architectures and lattice dimensions are preserved upon photopolymerization (see picture). Nanofibers resulting from the photopolymerization of the 2D structures are utilized as nanoreactors for Suzuki coupling reactions. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：650 / 653
页数：4
相关论文
共 28 条
[1]  
[Anonymous], ANGEW CHEM
[2]   Tailoring thermotropic cubic mesophases: amphiphilic polyhydroxy derivatives [J].
Borisch, K ;
Diele, S ;
Goring, P ;
Kresse, H ;
Tschierske, C .
JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (03) :529-543
[3]   Ordered bicontinuous nanoporous and nanorelief ceramic films from self assembling polymer precursors [J].
Chan, VZH ;
Hoffman, J ;
Lee, VY ;
Iatrou, H ;
Avgeropoulos, A ;
Hadjichristidis, N ;
Miller, RD ;
Thomas, EL .
SCIENCE, 1999, 286 (5445) :1716-1719
[4]   Mesophase structure-mechanical and ionic transport correlations in extended amphiphilic dendrons [J].
Cho, BK ;
Jain, A ;
Gruner, SM ;
Wiesner, U .
SCIENCE, 2004, 305 (5690) :1598-1601
[5]   Chain length-dependent three-dimensional organization of molecular rods with flexible coils [J].
Cho, BK ;
Lee, M ;
Oh, NK ;
Zin, WC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (39) :9677-9678
[6]  
DEMUS D, 1978, TEXTURE LIQUID CRYST
[7]  
Gray G.W.J.W.G. Goodby., 1984, SMECTIC LIQUID CRYST
[8]   Thin films of bicontinuous cubic mesostructured silica templated by a nonionic surfactant [J].
Hayward, RC ;
Alberius, PCA ;
Kramer, EJ ;
Chmelka, BF .
LANGMUIR, 2004, 20 (14) :5998-6004
[9]   About supramolecular assemblies of π-conjugated systems [J].
Hoeben, FJM ;
Jonkheijm, P ;
Meijer, EW ;
Schenning, APHJ .
CHEMICAL REVIEWS, 2005, 105 (04) :1491-1546
[10]   Structural inversion in 3-D hexagonal organization of coil-rod-coil molecule [J].
Jin, LY ;
Bae, J ;
Ahn, JH ;
Lee, M .
CHEMICAL COMMUNICATIONS, 2005, (09) :1197-1199
123