Benzoin derived reduced graphene oxide (rGO) and its nanocomposite: application in dye removal and peroxidase-like activity

被引:30
作者
Dutta, Soumen [1 ]
Sarkar, Sougata [1 ]
Ray, Chaiti [1 ]
Pal, Tarasankar [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India
关键词
EXFOLIATED GRAPHITE OXIDE; CHEMICAL-REDUCTION; ULTRAFAST REDUCTION; HYDROGEN SPILLOVER; CATALYTIC-ACTIVITY; ROOM-TEMPERATURE; FACILE SYNTHESIS; EFFICIENT ROUTE; NANOSHEETS; CARBON;
D O I
10.1039/c3ra44069a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Benzoin, a common reagent, has been used as a reducing agent for large scale production of reduced graphene oxide nanosheets and also for a gold-reduced graphene oxide nanocomposite (Au-rGO) by a co-reduction method. The pH of the reaction medium plays a crucial role in controlling the reaction kinetics. Systematic microscopic characterization reveals the sheet like nanostructure of reduced graphene oxide (rGO). A two-electron transfer mechanism has been proposed to support the reduction phenomenon. The reduced graphene oxide (rGO) has been successfully exploited for the removal of different dye molecules from aqueous solution and the recyclability has been tested. Here the adsorption capacity of the adsorbent is calculated to be 338.65 mg g(-1) for methylene blue. Finally peroxidase like activity of Au-rGO has been identified for pyrogallol oxidation using tert-butyl hydroperoxide.
引用
收藏
页码:21475 / 21483
页数:9
相关论文
共 74 条
[1]   Graphene Oxide-Based Hydrogels to Make Metal Nanoparticle-Containing Reduced Graphene Oxide-Based Functional Hybrid Hydrogels [J].
Adhikari, Bimalendu ;
Biswas, Abhijit ;
Banerjee, Arindam .
ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (10) :5472-5482
[2]   A novel strategy for making soluble reduced graphene oxide sheets cheaply by adopting an endogenous reducing agent [J].
Ai, Kelong ;
Liu, Yanlan ;
Lu, Lehui ;
Cheng, Xiaoli ;
Huo, Lihua .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (10) :3365-3370
[3]   Lithium Aluminum Hydride as Reducing Agent for Chemically Reduced Graphene Oxides [J].
Ambrosi, Adriano ;
Chua, Chun Kiang ;
Bonanni, Alessandra ;
Pumera, Martin .
CHEMISTRY OF MATERIALS, 2012, 24 (12) :2292-2298
[4]   Ex-MWNTs: Graphene Sheets and Ribbons Produced by Lithium Intercalation and Exfoliation of Carbon Nanotubes [J].
Cano-Marquez, Abraham G. ;
Rodriguez-Macias, Fernando J. ;
Campos-Delgado, Jessica ;
Espinosa-Gonzalez, Claudia G. ;
Tristan-Lopez, Ferdinando ;
Ramirez-Gonzalez, Daniel ;
Cullen, David A. ;
Smith, David J. ;
Terrones, Mauricio ;
Vega-Cantu, Yadira I. .
NANO LETTERS, 2009, 9 (04) :1527-1533
[5]   A route to high surface area, porosity and inclusion of large molecules in crystals [J].
Chae, HK ;
Siberio-Pérez, DY ;
Kim, J ;
Go, Y ;
Eddaoudi, M ;
Matzger, AJ ;
O'Keeffe, M ;
Yaghi, OM .
NATURE, 2004, 427 (6974) :523-527
[6]   Chemical Reduction of Graphene Oxide to Graphene by Sulfur-Containing Compounds [J].
Chen, Wufeng ;
Yan, Lifeng ;
Bangal, P. R. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (47) :19885-19890
[7]   Preparation of graphene by a low-temperature thermal reduction at atmosphere pressure [J].
Chen, Wufeng ;
Yan, Lifeng .
NANOSCALE, 2010, 2 (04) :559-563
[8]   Reduction of graphene oxide with substituted borohydrides [J].
Chua, Chun Kiang ;
Pumera, Martin .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (05) :1892-1898
[9]   Graphene oxide reduction by standard industrial reducing agent: thiourea dioxide [J].
Chua, Chun Kiang ;
Ambrosi, Adriano ;
Pumera, Martin .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (22) :11054-11061
[10]   The chemistry of graphene oxide [J].
Dreyer, Daniel R. ;
Park, Sungjin ;
Bielawski, Christopher W. ;
Ruoff, Rodney S. .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :228-240