Selective reduction of the acyl group in cyclic α-acyl-β-dicarbonyl compounds with sodium cyanoborohydride.: Efficient synthesis of cyclic α-alkyl-β-dicarbonyl compounds

被引：6

作者：

Pashkovsky, FS ^{[1
]}

Lokot', IP ^{[1
]}

Lakhvich, FA ^{[1
]}

机构：

[1] Natl Acad Sci Belarus, Inst Bioorgan Chem, Minsk 220141, BELARUS

来源：

RUSSIAN CHEMICAL BULLETIN | 2001年 / 50卷 / 02期

关键词：

cyclic alpha-acyl-beta-dicarbonyl compounds; sodium cyanoborohydride; selective reduction; cyclic alpha-alkyl-beta-dicarbonyl compounds;

D O I：

10.1023/A:1009511208712

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Efficient synthesis of cyclic alpha-alkyl-beta-dicarbonyl compounds of the cyclopentane, cyclohexane, tetronic acid, and alpha-pyrone series from the corresponding cyclic alpha-acyl-beta-dicarbonyl compounds under the action of NaBH3(CN) in a THF-HCl system is described.

引用

页码：324 / 326

页数：3