Synthesis, Structure and Photoluminescent Property of a New 3D Cd(II) Coordination Polymer with Terphenyl-2,2′,4,4′-tetracarboxylic Acid and 1,10-Phenanthroline

被引：0
|
作者：
Wang Ji-Jiang [1 ]
Hou Xiang-Yang [1 ]
Zhang Mei-Li [1 ]
Gao Lou-Jun [1 ]
Fu Feng [1 ]
机构：
[1] Yanan Univ, Shaanxi Key Lab Chem React Engn, Dept Chem & Chem Engn, Yanan 716000, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2013年 / 32卷 / 06期
基金：
中国国家自然科学基金;
关键词：
terphenyl-2,2 ',4,4 '-tetracarboxylic acid; Cd(II); photoluminescent property; ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new 3D Cd(II) coordination polymer, [Cd2L(phen)(H2O)](n) (1, H4L = terphenyl-2,2',4,4'-tetracarboxylic acid, phen = 1,10-phenanthroline), has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis, elemental analysis, TGA and IR spectroscopy. Complex 1 crystallizes in the monoclinic system, space group P2(1)/c with a = 8.196(2), b = 18.348(5), c = 19.036(5) angstrom, beta = 97.741(5)degrees, V = 2836.6(14) angstrom(3), Z = 4, D-c = 1.933 Mg.m(-3), mu = 1.565 mm(-1), F(000) = 1624, the final R = 0.0356 and wR = 0.0612 for 4990 observed reflections with I > 2 sigma(I). Complex 1 has a 1D chain containing Cd4 structural units, which are linked by 2- and 2'-carboxyl groups of L4- to result in a 3D framework. Additionally, the photoluminescent property of 1 was also studied in the solid state at room temperature.
引用
收藏
页码：949 / 953
页数：5
相关论文
共 50 条
  • [21] Synthesis, Structure and Photoluminescent Property of a New 2D Zn(II) Coordination Polymer Constructed by Biphenyl-3,3′,5,5′-tetracarboxylate
    Wang Ji-Jiang
    Cao Pei-Xiang
    Gao Lou-Jun
    Fu Feng
    Zhang Mei-Li
    Ren Yi-Xia
    Hou Xiang-Yang
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 30 (12) : 1787 - 1790
  • [22] Luminescence sensing, electrochemical, and magenetic properties of 2D coordination polymers based on the mixed ligands p-terphenyl-2,2′′,5′′,5′′′-tetracarboxylate acid and 1,10-phenanthroline
    Fan, Liming
    Liu, Zhangjie
    Zhang, Yujuan
    Wang, Feng
    Zhao, Dongsheng
    Yang, Jiandong
    Zhang, Xiutang
    NEW JOURNAL OF CHEMISTRY, 2019, 43 (34) : 13349 - 13356
  • [23] Synthesis, Structure and Luminescence Property of Cadmium(II) Coordination Polymer with Mixed 5-(Oxidediphenylphosphino)isophthalic Acid and 4,4′-Bipyridine Ligands
    Wen-Wen Shan
    Xiao Mi
    Jia-Yi Pu
    Shi-Le Mei
    Kai-Hui Li
    Chong-Zhen Mei
    Journal of Inorganic and Organometallic Polymers and Materials, 2013, 23 : 533 - 538
  • [24] Series metal-organic frameworks constructed from 1,10-phenanthroline and 3,3′,4,4′-biphenyltetracarboxylic acid: Hydrothermal synthesis, luminescence and photocatalytic properties
    Wang, Chong-chen
    Jing, Huan-ping
    Wang, Peng
    Gao, Shi-jie
    JOURNAL OF MOLECULAR STRUCTURE, 2015, 1080 : 44 - 51
  • [25] Versatile monometallic coordination polymers constructed from 4,4′-thiobis(methylene)bibenzoic acid and 1,10-phenanthroline. Synthesis, structure, magnetic and luminescence properties
    Wang, Shu-Ju
    Zhang, Zhi-Qing
    Jiang, Yi-Hui
    Xiong, Gang
    You, Li-Xin
    Ding, Fu
    Dragutan, Ileana
    Dragutan, Valerian
    Sun, Ya-Guang
    INORGANICA CHIMICA ACTA, 2022, 531
  • [26] Synthesis, Structure, and Properties of {[Mn(ADA)(Phen)]•(H2O)2}n Constructed from Azobenzene-4,4′-dicarboxylic Acid and 1,10-Phenanthroline
    Hou Xiang-Yang
    Wang Xiao
    Tang Long
    Wang Ji-Jiang
    Hou Xiu-Fang
    Kang Wei-Wei
    Liu Xiao-Li
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 37 (07) : 1125 - 1132
  • [27] Modular construction, magnetic property, and luminescent sensing of 3D Mn(II) and Cd(II) coordination polymers based on p-terphenyl-2,2",5",5"'-tetracarboxylate acid
    Fan, Liming
    Zhang, Yujuan
    Wang, Jiang
    Zhao, Li
    Wang, Xiaoqing
    Hu, Tuoping
    Zhang, Xiutang
    JOURNAL OF SOLID STATE CHEMISTRY, 2018, 260 : 46 - 51
  • [28] Synthesis, Structure, and Photoluminescent Properties of Zn2+, Mn2+, Cd2+, Eu3+, and Tb3+ Complexes with 4-Allyl-2,3,5,6-Tetrafluorobenzoic Acid Anions and 1,10-Phenanthroline
    Shmelev, M. A.
    Chistyakov, A. S.
    Razgonyaeva, G. A.
    Voronina, J. K.
    Varaksina, E. A.
    Taydakov, I. V.
    Sidorov, A. A.
    Eremenko, I. L.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2024, 65 (02) : 362 - 380
  • [29] A 3D cadmium(II) coordination polymer constructed from new β-diketone-functionalized pyridinecarboxylate and 4,4′-bipyridine ligands
    Chen, Qing
    Chen, Xiao-Li
    Hu, Huai-Ming
    Sha, Hui-Ming
    Fu, Feng
    Yang, Meng-Lin
    Xue, Gang-Lin
    INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 44 : 143 - 147
  • [30] 4,4′-(1,2-Phenylenebis(methyleneoxy))dibenzoate based Cd (II)-coordination polymer: A turn-off-on photoluminescent sensor against ascorbic acid and aspirin
    Fang, Jiajun
    Ayue, Yiguo
    Liang, Jingyi
    Lu, Lu
    Parvez, Mohammad Khalid
    Al-Dosari, Mohammed S.
    Srivastava, Shreya
    Kumar, Abhinav
    MICROCHEMICAL JOURNAL, 2025, 211
12345