Synthesis, Structure and Photoluminescent Property of a New 3D Cd(II) Coordination Polymer with Terphenyl-2,2′,4,4′-tetracarboxylic Acid and 1,10-Phenanthroline

被引：0
|
作者：
Wang Ji-Jiang [1 ]
Hou Xiang-Yang [1 ]
Zhang Mei-Li [1 ]
Gao Lou-Jun [1 ]
Fu Feng [1 ]
机构：
[1] Yanan Univ, Shaanxi Key Lab Chem React Engn, Dept Chem & Chem Engn, Yanan 716000, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2013年 / 32卷 / 06期
基金：
中国国家自然科学基金;
关键词：
terphenyl-2,2 ',4,4 '-tetracarboxylic acid; Cd(II); photoluminescent property; ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new 3D Cd(II) coordination polymer, [Cd2L(phen)(H2O)](n) (1, H4L = terphenyl-2,2',4,4'-tetracarboxylic acid, phen = 1,10-phenanthroline), has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis, elemental analysis, TGA and IR spectroscopy. Complex 1 crystallizes in the monoclinic system, space group P2(1)/c with a = 8.196(2), b = 18.348(5), c = 19.036(5) angstrom, beta = 97.741(5)degrees, V = 2836.6(14) angstrom(3), Z = 4, D-c = 1.933 Mg.m(-3), mu = 1.565 mm(-1), F(000) = 1624, the final R = 0.0356 and wR = 0.0612 for 4990 observed reflections with I > 2 sigma(I). Complex 1 has a 1D chain containing Cd4 structural units, which are linked by 2- and 2'-carboxyl groups of L4- to result in a 3D framework. Additionally, the photoluminescent property of 1 was also studied in the solid state at room temperature.
引用
收藏
页码：949 / 953
页数：5
相关论文
共 50 条
  • [21] Synthesis and Characterization of a New 3D Pillared Bilayer Cd(II) Coordination Polymer Based on 6,6′-Dinitro-2,2′,4,4′-biphenyltetracarboxylic Acid
    Wang Ji-Wu
    Su Yong-Chao
    Wang Ji-Jiang
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 34 (09) : 1385 - 1390
  • [22] Synthesis, Crystal Structure and Property of the Transition Metal(II) Coordination Polymers with 3-Fluorophthalic Acid and 1,10-Phenanthroline
    Song Shuang
    Cha Yu-E
    Wang Yu-Feng
    Liu Yi-Heng
    Li Xia
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2014, 30 (06) : 1234 - 1242
  • [23] Utilization of mixed ligands to construct diverse Ni(II)-coordination polymers based on terphenyl-2,2′,4,4′-tetracarboxylic acid and varied N-donor co-ligands
    Wang, Chao
    Zhao, Jun
    Xia, Liang
    Wu, Xue-Qian
    Wang, Jian-Fang
    Dong, Wen-Wen
    Wu, Ya-Pan
    JOURNAL OF SOLID STATE CHEMISTRY, 2016, 238 : 273 - 278
  • [24] Syntheses, structures, and magnetism of two coordination compounds with 3,3′,4,4′-biphenyltetracarboxylic acid and 1,10-phenanthroline
    Zhang, Sheng
    Xie, Gang
    Zou, Yanhua
    Chen, Sanping
    Gao, Shengli
    JOURNAL OF COORDINATION CHEMISTRY, 2012, 65 (06) : 1062 - 1070
  • [25] Synthesis, Structure and Characterization of Pb(II) Coordination Polymer Constructed by 1,10-Phenanthroline Derivative and Succinic Acid
    Kong Zhi-Guo
    Sun Xu-Ran
    Li He
    Fan Yan-Jia
    Zhang Lin
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2013, 29 (09) : 1942 - 1946
  • [26] An improved synthesis of 4-cyano-1,10-phenanthroline, 4,7-dicyano-1,10-phenanthroline and their bis (4,4'-di-tert-butyl-2,2'-bipyridine)ruthenium(II) complexes
    Staehle, Robert
    Menzel, Roberto
    Peuntinger, Katrin
    Pilz, T. David
    Heinemann, Frank W.
    Guldi, Dirk M.
    Beckert, Rainer
    Rau, Sven
    POLYHEDRON, 2014, 73 : 30 - 36
  • [27] Synthesis, structure and sensing behavior of a Cd-coordination polymer based on 1,10-phenanthroline and 2-aminoterephthalic acid
    Meng, Xing
    Wang, Hai-Feng
    Chen, He
    Zhou, Zi-Yan
    Wang, Hai-Ning
    FUNCTIONAL MATERIALS LETTERS, 2018, 11 (02)
  • [28] Synthesis and crystal structure of a new three-dimensional Cd(II) coordination polymer based on 4,4′-bipyridine and 3,3′,4,5′-biphenyl tetracarboxylic acid
    Li, Shi-Hui
    INORGANIC AND NANO-METAL CHEMISTRY, 2022, 52 (01) : 108 - 111
  • [29] A Fe(II) Coordination Polymer Based on 1,10-Phenanthroline Derivative and Oxalic Acid: Synthesis, Structure, and Properties(1)
    Li Xiu-Ying
    Gao Lin
    Che Guang-Bo
    Yan Yong-Sheng
    Li Chun-Xiang
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 40 (03) : 317 - 323
  • [30] Synthesis, structure, and magnetic property of a 3D supramolecular Gd(III) coordination polymer with 4,4′-sulfonyldibenzoic acid ligands
    X. N. Zhang
    Z. B. Han
    Russian Journal of Coordination Chemistry, 2015, 41 : 334 - 338
12345