Synthesis and structures of the triple-decker type complexes CpCo(μ-1,3-C3B2Me5)MX2L (M=Rh and Ir; X=Cl and Br; L=Me2SO and PPh3)

被引：0

作者：

Romanov, Alexander S. ^{[1
,2
]}

Muratov, Dmitry V. ^{[1
]}

Antipin, Mikhail Yu ^{[1
,2
]}

Siebert, Walter ^{[3
]}

Kudinov, Alexander R. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Organoelement Cpds, Moscow 119991, Russia

[2] New Mexico Highlands Univ, Dept Nat Sci, Las Vegas, NM 87701 USA

[3] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2012年 / 715卷

关键词：

Boron; Cobalt; Heterocycles; Rhodium; Iridium; Triple-decker complexes; RHODIUM; LIGANDS; HYDROGENATION;

D O I：

10.1016/j.jorganchem.2012.06.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dimeric triple-decker type halides [CpCo(mu-1,3-C3B2Me5)MX2](2) (M = Rh, X = Cl, 1; M = Ir, X = Cl, 2; M = Rh, X = Br, 3; M = Ir, X = Br, 4) react with Me2SO and PPh3 giving adducts CpCo(mu-1,3-C3B2Me5) M(L) X-2 (5-12). The Me2SO ligand is S-bonded to the metal atom in the solid state, while in acetone it is O-bonded. Structures of 5-12 were confirmed by X-ray diffraction. (C) 2012 Elsevier B. V. All rights reserved.

引用

页码：136 / 140

页数：5

共 36 条

[21] New half-sandwich heterobimetallic CpMPt (M = Rh, Ir) dithiolato bridged complexes.: X-ray structure of [(PPh3)2Pt(μ-S(CH2)2S)RhCl(η5-C5H5)]BF4
Forniés-Cámer, J
Claver, C
Masdeu-Bultó, AM
Cardin, CJ
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 662 (1-2) : 188 - 191
[22] Energetics of the oxidative addition of I-2 to [Ir(CL-L)(CO)(2)](2) (L=S(t)Bu,3,5-Me(2)pz,7-aza) complexes. X-ray structures of [Ir(mu S(t)Bu)(I)(CO)(2)](2) and [Ir(mu-3,5-Me(2)pz)(I)(CO)(2)](2)
Ciriano, MA
Dias, AR
Nunes, PM
Oro, LA
daPiedade, MFM
daPiedade, MEM
daSilva, PF
Simoes, JAM
PerezTorrente, JJ
Veiros, LF
STRUCTURAL CHEMISTRY, 1996, 7 (5-6) : 337 - 354
[23] Modified synthesis of mixed-ligand dinuclear Ru-Ir, Ru-Rh, and Ru-Ru polyhydride-bridged complexes, CpsRuH3ML (Cps = C5Me5 (Cp*), C5tBu3H2 (Cp‡); M = Rh, Ir, Ru; L = C5(CH3)5, C6H6, p-CH3C6H4CH(CH3)2)
Shimogawa, Ryuichi
Takao, Toshiro
Suzuki, Hiroharu
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2016, 818 : 168 - 178
[24] Mixed-metal cluster chemistry 25 Mixed ligand derivatives of MoIr3(μ-CO)3(CO)8(η-C5R5) (R = H, Me) and Mo2Ir2(μ-CO)3(CO)7(η-C5H5)2;: X-ray crystal structures of MoIr3(μ-CO)3(CO)6(PPh3)2(η-C5Me5) and Mo2Ir2(μ4-η2-PhC2Ph)(μ-CO)4(CNBut)(CO)3(η-C5H5)2
Usher, AJ
Humphrey, MG
Willis, AC
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 682 (1-2) : 41 - 48
[25] Half-Sandwich B-Oxy Boratabenzene Ruthenium Complexes: Synthesis, Characterization, and Reactivity of (η6-C5H5BOR)RuCl(PPh3)2 (R = Et, Me)
Li, Ting
Fu, Chen
Liu, Zi
Guo, Shuiliang
Liu, Zicheng
Wen, Ting-Bin
ORGANOMETALLICS, 2015, 34 (13) : 3292 - 3302
[26] Synthesis and spectroscopic properties of some new bi-, tri- and tetrametallic complexes of the type [M(CO)(5)L], [M(CO)(4)L-2] and [M(CO)(3)L-3] {M=Cr, Mo, W; L=[(WI2(CO){Ph2P(CH2)(2)P)over-bar-Ph(CH2)(2)PPh2-P,P'}(eta(2)-RC2R')] (R=R'=Me, Ph; R=Me, R'=Ph)}
Baker, PK
Meehan, MM
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 535 (1-2) : 129 - 134
[27] Structure and Bonding Energy Analysis of Cobalt, Rhodium, and Iridium Borylene Complexes [(η5-C5H5)(CO)M(BNX2] (X = Me, SiH3, SiMe3) and [(η5-C5H5)(PMe3)M{BN(SiH3)2}] (M = Co, Rh, Ir)
Pandey, Krishna K.
Musaev, Djamaladdin G.
ORGANOMETALLICS, 2010, 29 (01) : 142 - 148
[28] Catalytic and stoichiometric reactions of tertiary silanes with [Ir(Me)2Cp*L] (Cp* = η5-C5Me5; L = PMe3, PMe2Ph, PMePh2, PPh3) in the presence of one-electron oxidants.: A unique case of Si-H, Si-C, Ir-C and P-F bonds one-step activation:: crystal structure of [Ir(Ph)(SiPh2F)Cp*(PMe3)]
Diversi, P
Marchetti, F
Ermini, V
Matteoni, S
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 593 : 154 - 160
[29] Synthesis, characterization and crystal structures of osmium-rhodium mixed-metal clusters containing pentamethylcyclopentadienyl ligand:: [Os3Rh(μ-CO)2(CO)9(η5-Cp*)], [Os3Rh2(μ-H)(μ-CO)2(CO)8(η5-Cp*)(μ2-η5,η1-CH2C5Me4)] and [Os3Rh(μ3-H)(μ-Cl) (μ-CO)(CO)9(η5-Cp*)]
Hung, SYW
Wong, WT
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 580 (01) : 48 - 55
[30] Heterometallic Trinuclear Polyhydrido Complexes Containing Ruthenium and a Group 9 Metal, [Cp*3Ru2M(μ3-H)(μ-H)3] (M = Ir or Rh; Cp* = η5-C5Me5): Synthesis, Structure, and Site Selectivity in Reactions with Phosphines
Shima, Takanori
Sugimura, Yumi
Suzuki, Hiroharu
ORGANOMETALLICS, 2009, 28 (03) : 871 - 881

← 1 2 3 4 →