Synthesis of spiro 1,3-oxazolidines via palladium-catalyzed [3+2] cycloaddition of vinyl epoxides with cyclohexadienimines

被引：5
|
作者：
Qin, Shaoheng [1 ]
He, Qiuqin [2 ]
Wang, Jingyun [1 ]
Zhou, Ming-Dong [1 ]
机构：
[1] Liaoning Shihua Univ, Sch Chem & Mat Sci, 1 Dandong Rd, Fushun 113001, Peoples R China
[2] Fudan Univ, Dept Chem, 220 Handan Rd, Shanghai 200433, Peoples R China
来源：
JOURNAL OF SAUDI CHEMICAL SOCIETY | 2020年 / 24卷 / 06期
关键词：
Spiro 1,3-oxazolidine; Palladium-catalyzed; Cycloaddition; ENANTIOSELECTIVE SYNTHESIS; VINYLOXIRANES; OXIRANES; ROUTE; CONSTRUCTION; DERIVATIVES; ACTIVATION; IMINES;
D O I：
10.1016/j.jscs.2020.03.008
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A palladium-catalyzed chemoselective [3 + 2] cycloaddition of vinyl epoxide with cyclohexadienimines was developed. The reaction gave rise to a range of spiro 1,3-oxazolidines in moderate to good yields. (C) 2020 Published by Elsevier B.V. on behalf of King Saud University.
引用
收藏
页码：445 / 450
页数：6
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