Self-assembly of nanocrystalline tetra-terpyridine complexes: from molecules to mesoscopic objects

被引：11

作者：

Molloy, Jennifer K. ^{[1
]}

Ceroni, Paola ^{[1
]}

Venturi, Margherita ^{[1
]}

Bauer, Thomas ^{[2
]}

Sakamoto, Junji ^{[2
]}

Bergamini, Giacomo ^{[1
]}

机构：

[1] Dept Chem G Ciamician, I-40126 Bologna, Italy

[2] ETH, Inst Polymers, Dept Mat, HCI G 523, CH-8093 Zurich, Switzerland

来源：

SOFT MATTER | 2013年 / 9卷 / 45期

关键词：

ABSORPTION-SPECTRA; CHEMISTRY; WHEEL; 2D;

D O I：

10.1039/c3sm52353e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the properties of a shape-persistent tetra-terpyridine ligand whose coordination to transition metal ions guides its three-dimensional self-assembly in two steps: at first, nanoscale objects form, which with time, self-assemble into micrometer structures. This work highlights the potential for control of the molecular self-assembly of molecules on the nanoscale, and the successive self-assembly of the formed supramolecular nanosystems to yield mesoscopic objects.

引用

收藏

页码：10754 / 10758

页数：5

相关论文

共 26 条

[1]

Balzani V., 2008, MOL DEVICES MACHINES, DOI DOI 10.1002/9783527621682

[2] Homo- and heterometallic [2 x 2] grid arrays containing RuII, OsII, and FeII subunits and their mononuclear RuII and OsII precursors:: Synthesis, absorption spectra, redox behavior, and luminescence properties [J].

Bassani, DM ;

Lehn, JM ;

Serroni, S ;

Puntoriero, F ;

Campagna, S .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (23) :5936-5946

[3] Synthesis of Free-Standing, Monolayered Organometallic Sheets at the Air/Water Interface [J].

Bauer, Thomas ;

Zheng, Zhikun ;

Renn, Alois ;

Enning, Raoul ;

Stemmer, Andreas ;

Sakamoto, Junji ;

Schlueter, A. Dieter .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (34) :7879-7884

[4] Towards 2D and 3D Coordination Polymers: Synthesis of Shape-Persistent Star Monomers with 2,2′:6′,2"-Terpyridin-4′-yl Units at the Periphery [J].

Bauer, Thomas ;

Schlueter, A. Dieter ;

Sakamoto, Junji .

SYNLETT, 2010, (06) :877-880

[5] Molecule-mimetic chemistry and mesoscale self-assembly [J].

Bowden, NB ;

Weck, M ;

Choi, IS ;

Whitesides, GM .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (03) :231-238

[6] ELECTRONIC ABSORPTION-SPECTRA OF THE IRON(II) COMPLEXES OF 2,2'-BIPYRIDINE, 2,2'-BIPYRIMIDINE, 1,10-PHENANTHROLINE, AND 2,2'-6',2''-TERPYRIDINE AND THEIR REDUCTION PRODUCTS [J].

BRATERMAN, PS ;

SONG, JI ;

PEACOCK, RD .

INORGANIC CHEMISTRY, 1992, 31 (04) :555-559

[7] Engineering of an iron-terpyridine complex with supramolecular gels and mesomorphic properties [J].

Camerel, F ;

Ziessel, R ;

Donnio, B ;

Guillon, D .

NEW JOURNAL OF CHEMISTRY, 2006, 30 (02) :135-139

[8] Higher-order organization by mesoscale self-assembly and transformation of hybrid nanostructures [J].

Cölfen, H ;

Mann, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (21) :2350-2365

[9] 2,2′: 6′,2"-terpyridines:: From chemical obscurity to common supramolecular motifs [J].

Constable, Edwin C. .

CHEMICAL SOCIETY REVIEWS, 2007, 36 (02) :246-253

[10] Recent developments in the supramolecular chemistry of terpyridine-metal complexes [J].

Hofmeier, H ;

Schubert, US .

CHEMICAL SOCIETY REVIEWS, 2004, 33 (06) :373-399