Metallomicelles of palladium(II) complexes as efficient catalysts for the Suzuki-Miyaura reaction in neat water

被引：13

作者：

Liu, Yan ^{[1
]}

Ma, Xiaowei ^{[1
]}

Xie, Jianwei ^{[1
]}

Liu, Ping ^{[1
]}

Dai, Bin ^{[1
]}

He, Ren ^{[2
]}

机构：

[1] Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Shihezi 832003, Peoples R China

[2] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2013年 / 27卷 / 08期

基金：

中国国家自然科学基金;

关键词：

metallomicelles; palladium(II) complexes; Suzuki-Miyaura reaction; water; liquid crystalline compounds; CROSS-COUPLING REACTIONS; SURFACTANT CO(III) COMPLEXES; SUPERCRITICAL CARBON-DIOXIDE; ORGANOBORON COMPOUNDS; ARYL CHLORIDES; IONIC LIQUIDS; ACID; NANOPARTICLES; DERIVATIVES; GRAPHENE;

D O I：

10.1002/aoc.3021

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Metallomicelles of palladium(II) complex 4 are found to be an efficient catalyst for Suzuki-Miyaura reactions of aryl bromides substituted with a long alkyl chain and arylboronic acids at 80 degrees C in neat water. The reactions proceed smoothly to generate the corresponding biaryl compounds in moderate to excellent yields. Various biphenyl derivatives were successfully obtained by complex 4 catalysis of the Suzuki-Miyaura reactions in the absence of any surfactants in neat water. Copyright (c) 2013 John Wiley & Sons, Ltd.

引用

页码：494 / 498

页数：5

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