Structure of two-dimensional rods confined by a line boundary

被引:27
作者
Chen, Jeff Z. Y. [1 ]
机构
[1] Univ Waterloo, Dept Phys & Astron, Waterloo, ON N2L 3G1, Canada
关键词
ISOTROPIC-NEMATIC INTERFACE; HARD SPHEROCYLINDERS; ORIENTATIONAL ORDER; FREE-ENERGY; MODEL; POLYMERS;
D O I
10.1039/c3sm51991k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In two dimensions, a nematic liquid crystal displays a two-fold rotational symmetry about the normal to the embedding surface. A confining line boundary that restricts the system within an area can geometrically frustrate the system, creating a defective structure in orientation. On the basis of the generalized Onsager model, we present the free energy as a function of the particle density distribution for systems under a square or circular confinement. The numerical solution of the model explains the coupled orientational and directional order observed experimentally.
引用
收藏
页码:10921 / 10930
页数:10
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