In situ synthesis of block copolymer nano-assemblies by polymerization-induced self-assembly under heterogeneous condition

被引：81
|
作者：
Chen, Sheng-li [1 ]
Shi, Peng-fei [1 ]
Zhang, Wang-qing [1 ,2 ]
机构：
[1] Nankai Univ, Inst Polymer Chem, Key Lab Funct Polymer Mat, Minist Educ, Tianjin 300071, Peoples R China
[2] Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China
来源：
CHINESE JOURNAL OF POLYMER SCIENCE | 2017年 / 35卷 / 04期
基金：
中国国家自然科学基金; 美国国家科学基金会;
关键词：
Block copolymers; Self-assembly; Emulsion RAFT polymerization; Dispersion RAFT polymerization; Seeded RAFT polymerization; RAFT DISPERSION POLYMERIZATION; CONTROLLED/LIVING RADICAL POLYMERIZATION; SEEDED EMULSION POLYMERIZATION; SUPERCRITICAL CARBON-DIOXIDE; CORE-SHELL NANOPARTICLES; ONE-POT SYNTHESIS; DIBLOCK COPOLYMER; MOLECULAR-WEIGHT; MULTICOMPARTMENT NANOPARTICLES; MEDIATED POLYMERIZATION;
D O I：
10.1007/s10118-017-1907-8
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Controlled synthesis of amphiphilic block copolymer nanoparticles in a convenient way is an important and interest topic in polymer science. In this review, three formulations of polymerization-induced self-assembly to in situ synthesize block copolymer nanoparticles are briefly introduced, which perform by reversible addition-fragmentation chain transfer (RAFT) polymerization under heterogeneous conditions, e.g., aqueous emulsion RAFT polymerization, dispersion RAFT polymerization and especially the recently proposed seeded RAFT polymerization. The latest developments in several selected areas on the synthesis of block copolymer nano-assemblies are highlighted.
引用
收藏
页码：455 / 479
页数：25
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