Graphene Oxide as a Metal-free Carbocatalyst for Direct Amide Synthesis from Carboxylic Acid and Amine Under Solvent-Free Reaction Condition

被引：9

作者：

Patel, Khushbu P. ^{[1
]}

Gayakwad, Eknath M. ^{[1
]}

Shankarling, Ganapati S. ^{[1
]}

机构：

[1] Inst Chem Technol, MatDept Dyestuff Technol, Inst Chem Technol, Dept Dyestuff Technol, NP Marg, Mumbai 400019, Maharashtra, India

来源：

CHEMISTRYSELECT | 2020年 / 5卷 / 27期

关键词：

Amides; Metal-free approach; Green chemistry; Heterogeneous catalysis; Recyclability; Solvent-free reaction condition; ONE-POT SYNTHESIS; EFFICIENT CATALYST; DIRECT AMIDATION; GRAPHITE OXIDE; TRANSAMIDATION; CARBOXAMIDES; CONVENIENT; OXIDATION;

D O I：

10.1002/slct.202000870

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, a highly efficient, metal-free, carbocatalyst, graphene oxide (GO) has been screened for the direct amidation of carboxylic acids with amines. The present catalytic system accessed a broad range of substrates to afford amides in excellent yields. A plausible reaction mechanism involving H-bonding with the reactants is described. Furthermore, the GO can be recycled and reused up to five cycles without substantial loss in catalytic activity.

引用

收藏

页码：8295 / 8300

页数：6

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