In geological imaging spectrometry (i.e., hyperspectral remote sensing), surface compositional information (e.g., mineralogy and subsequently chemistry) is obtained by statistical comparison (by means of spectral matching algorithms) of known field- or library spectra to unknown image spectra. Though these algorithms are readily used, little emphasis has been given to comparison of the performance of the various spectral matching algorithms. Four spectral measures are presented: three that calculate the angle (spectral angle measure, SAM), the vector distance (Euclidean distance measure, ED) or the vector crosscorrelation (spectral correlation measure, SCM), between a known reference and unknown target spectrum and a fourth measure that measures the discrepancy of probability distributions between two pixel vectors (the spectral information divergence, SID). The performance of these spectral similarity measures is compared using synthetic hyperspectral and real (i.e., Airborne Visible Infrared Imaging Spectrometer, AVIRIS) hyperspectral data of a (artificial or real) hydrotherntat alteration system characterised by the minerals alunite. kaolinite, montmorillonite and quartz. Two statistics are used to assess the performance of the spectral similarity measures: the probability of spectral discrimination (PSD) and the power of spectral discrimination (PWSD). The first relates to the ability of the selected set of spectral endmembers to map a target spectrum, whereas the second expresses the capability of a spectral measure to separate two classes relative to a reference class. Analysis of the synthetic data set (i.e., simulated alteration zones with crisp boundaries at 1-2 nm spectral resolution) shows that (1) the SID outperforms the classical empirical spectral matching techniques (SAM, SCM and ED), (2) that SCM (SID, SAM and ED do not) exploits the overall shape of the reflectance curve and hence its outcomes are (positively and negatively) affected by the spectral range selected, (3) SAM and ED give nearly similar results and (4) for the same reason as in (2), the SCM is also more sensitive (again in positive and negative sense) to the spectral noise added. Results from the study of AVIRIS data show that SAM yields more spectral confusion (i.e., class overlap) than SID and SCM. In turn, SID is more effective in mapping the four target minerals than SCM as it clearly outperforms SCM when the target mineral coincides with the mineral phase on the ground. (c) 2005 Elsevier B.V. All rights reserved.
