On the relative magnitudes of cis and trans influences in metal complexes

被引：84

作者：

Anderson, KM ^{[1
]}

Orpen, AG ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 24期

关键词：

D O I：

10.1039/b108517b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cis and trans influences are of similar magnitude in octahedral complexes of Sn-IV and Sb-V while the trans influence is dominant in square planar Pt-II (d(8)) and d(6)-ML6 cases.

引用

页码：2682 / 2683

页数：2

共 19 条

[1]

Allen F.H., 1993, CHEM AUTOMAT NEWS, V8, P31

[2]

ALLEN FH, 1993, CHEM DESIGN AUTOMATI, V8, P1

[3] TRANS-INFLUENCE - ITS MEASUREMENT AND SIGNIFICANCE [J].

APPLETON, TG ;

CLARK, HC ;

MANZER, LE .

COORDINATION CHEMISTRY REVIEWS, 1973, 10 (3-4) :335-422

[4] N-15 AND PT-195 NMR-SPECTRA OF PLATINUM AMMINE COMPLEXES - TRANSINFLUENCE AND CIS-INFLUENCE SERIES BASED ON PT-195-N-15 COUPLING-CONSTANTS AND N-15 CHEMICAL-SHIFTS [J].

APPLETON, TG ;

HALL, JR ;

RALPH, SF .

INORGANIC CHEMISTRY, 1985, 24 (26) :4685-4693

[5] Heterocyclic systems containing tin(IV)-XIII .1. Possible ceasing or inversion of the structural trans influence during the course of a bimolecular nucleophilic attack of a donor group in a series of Sn-IV rings [J].

Beuter, M ;

Kolb, U ;

Zickgraf, A ;

Brau, E ;

Bletz, M ;

Drager, M .

POLYHEDRON, 1997, 16 (23) :4005-4015

[6] TRANS INFLUENCE AND MUTUAL INFLUENCE OF LIGANDS COORDINATED TO A CENTRAL ATOM [J].

BURDETT, JK ;

ALBRIGHT, TA .

INORGANIC CHEMISTRY, 1979, 18 (08) :2112-2120

[7] Trans-effects in octahedral transition metal complexes [J].

Coe, BJ ;

Glenwright, SJ .

COORDINATION CHEMISTRY REVIEWS, 2000, 203 :5-80

[8] THE TRANS INFLUENCE IN [RH(PH3)3CL] - A DENSITY-FUNCTIONAL THEORY STUDY [J].

DEETH, RJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (24) :3711-3713

[9]

GREENWOOD NN, 1997, CHEM ELEMENTS, P1164

[10]

HOUSECROFT CE, 2001, INORG CHEM, P574

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