Deep Purification of Lithium Compounds to Remove Chemical and Radioactive Impurities

被引：1

作者：

Milyutin, V. V. ^{[1
]}

Kaptakov, V. O. ^{[1
]}

Nekrasova, N. A. ^{[1
]}

Rudskikh, V. V. ^{[1
,2
]}

Volkova, T. S. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow 119071, Russia

[2] Mayak Prod Assoc, Ozersk 456780, Chelyabinsk Obl, Russia

来源：

RADIOCHEMISTRY | 2020年 / 62卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

lithium hydroxide; chemical impurities; radioactive impurities; ultrafiltration; sorption; ion exchangers;

D O I：

10.1134/S1066362220030054

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Possibility of performing deep purification of lithium hydroxide solutions to remove admixtures of alkaline-earth and transition metals, magnesium, aluminum, uranium, thorium, and radium radionuclides (strontium) by using the sorption and membrane methods has been examined. It was shown that successive procedures of mechanical filtration, ultrafiltration with a ceramic membrane having pore size of 50 nm, and sorption purification on an imine carboxyl cation exchanger make it possible to obtain lithium carbonate with no less than 99.9% main substance. The content of impurities being determined in the sample obtained does not exceed 0.005-0.01 wt %. The specific activity of a sample as regards the sum of alpha- and beta-emitters does not exceed their lower detection limit (less than 0.1 Bq/g).

引用

页码：331 / 334

页数：4

共 9 条

[1] Bolshakov K.A., 1976, Chemistry and Technology of Rare and Trace Elements. Part 2
[2] Korovin S.S., 1996, Rare and diffused elements. Chemistry and Technology
[3] Kotsupalo N.P., 2008, KHIMIYA TEKHNOLOGIYA
[4] Kulifeev V.K., 2006, Litii (Lithium)
[5] Lidin R.A., 1987, SPRAVOCHNIK NEORGANI
[6] Removal of Radionuclides and Corrosion Products from Neutral and Weakly Alkaline Solutions by Microfiltration
Milyutin, V. V.
Nekrasova, N. A.
Kaptakov, V. O.
[J]. RADIOCHEMISTRY, 2016, 58 (01) : 30 - 33
[7] [Милютин Виталий Витальевич Milyutin Vitaliy V.], 2018, [Сорбционные и хроматографические процессы, Sorption and Chromatography Processes, Sorbtsionnye i khromatograficheskie protsessy], V18, P365
[8] Ryabchikov B.E., 2008, Purification of Liquid Radioactive Waste
[9] Saldadze K.N., 1980, KOMPLEKSOOBRAZUYUSHC

← 1 →