Synthesis and initial transition metal chemistry of the first PGeP pincer-type germylene

被引：47

作者：

Alvarez-Rodriguez, Lucia ^{[1
,2
]}

Brugos, Javier ^{[1
,2
]}

Cabeza, Javier A. ^{[1
,2
]}

Garcia-Alvarez, Pablo ^{[1
,2
]}

Perez-Carreno, Enrique ^{[3
]}

Polo, Diego ^{[1
,2
]}

机构：

[1] Univ Oviedo, CSIC, ORFEO CINQ, Ctr Innovac Quim Avanzada, E-33071 Oviedo, Spain

[2] Univ Oviedo, CSIC, IUQOEM, Dept Quim Organ & Inorgan, E-33071 Oviedo, Spain

[3] Univ Oviedo, Dept Quim Fis & Analit, E-33071 Oviedo, Spain

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 05期

关键词：

N-HETEROCYCLIC GERMYLENES; SPECTROSCOPIC PROPERTIES; IRIDIUM COMPLEXES; ACTIVATION; LIGAND; (PHOSPHINOALKYL)SILANES; STEREOMUTATION; BIS(SILYLENE); COORDINATION; STANNYLENES;

D O I：

10.1039/c6cc09283g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A PGeP pincer-type germylene, Ge((NCH2PBu2)-Bu-t)(2)C6H4, which contains two phosphane groups hanging from the N atoms of an N-heterocyclic germylene fragment, has been isolated for the first time. This compound has already furnished a rich transition metal derivative chemistry (Co, Rh, and Pd) that includes complexes containing bridging P,Ge,P-, chelating P,Ge- and pincer P,Ge,P-ligands.

引用

页码：893 / 896

页数：4

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