Palladium pincer complexes with reduced bond angle strain: Efficient catalysts for the Heck reaction

被引:52
作者
Yoon, Myeong Sik [1 ]
Ryu, Dowook [1 ]
Kim, Jeongryul [1 ]
Ahn, Kyo Han [1 ]
机构
[1] POSTECH, Dept Chem, Pohang 790784, South Korea
关键词
D O I
10.1021/om0601246
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Palladium pincer complexes composed of six-membered fused metallacycles have been synthesized directly from 1,3-bis(2-pyridyloxy)benzene. The pincer complexes show remarkably high turnover numbers and frequencies in the Heck reaction.
引用
收藏
页码:2409 / 2411
页数:3
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