Ordered mesoporous MoO2 as a high-performance anode material for aqueous supercapacitors

被引:107
作者
Li, Xinyong
Shao, Jie
Li, Jing
Zhang, Li
Qu, Qunting [1 ]
Zheng, Honghe
机构
[1] Soochow Univ, Sch Energy, Suzhou 215006, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
Aqueous supercapacitors; Anode; Molybdenum dioxide; Mesoporous; ELECTROCHEMICAL CAPACITORS; FACILE SYNTHESIS; OXIDE; ALPHA-MOO3; NANOWIRES; NANORODS; ELECTROLYTES; ELECTRODES; NANOBELTS; GRAPHENE;
D O I
10.1016/j.jpowsour.2013.03.020
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ordered mesoporous MoO2 is prepared employing silica KIT-6 as hard template. Electrochemical quartz crystal microbalance is utilized to investigate the charge storage mechanism of rnesoporous MoO2 in aqueous LiOH electrolyte solution. The dominating working ions are proved to be Li+ ions. Mesoporous MoO2 exhibits excellent supercapacitive behavior in the potential range of -1.2 to -0.5 V vs. SCE, rendering it a promising anode material for aqueous supercapacitors. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:80 / 83
页数:4
相关论文
共 28 条
[1]  
Brezesinski T, 2010, NAT MATER, V9, P146, DOI [10.1038/NMAT2612, 10.1038/nmat2612]
[2]   Templated Nanocrystal-Based Porous TiO2 Films for Next-Generation Electrochemical Capacitors [J].
Brezesinski, Torsten ;
Wang, John ;
Polleux, Julien ;
Dunn, Bruce ;
Tolbert, Sarah H. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (05) :1802-1809
[3]   Template-free approach to synthesize hierarchical porous nickel cobalt oxides for supercapacitors [J].
Chang, Jie ;
Sun, Jing ;
Xu, Chaohe ;
Xu, Huan ;
Gao, Lian .
NANOSCALE, 2012, 4 (21) :6786-6791
[4]   From Graphene to Metal Oxide Nanolamellas: A Phenomenon of Morphology Transmission [J].
Chen, Sheng ;
Zhu, Junwu ;
Wang, Xin .
ACS NANO, 2010, 4 (10) :6212-6218
[5]   Fabrication horizontal aligned MoO2/single-walled carbon nanotube nanowires for electrochemical supercapacitor [J].
Gao, Fenglei ;
Zhang, Lijie ;
Huang, Shaoming .
MATERIALS LETTERS, 2010, 64 (04) :537-540
[6]   From MoO3 Nanobelts to MoO2 Nanorods: Structure Transformation and Electrical Transport [J].
Hu, Bin ;
Mai, Liqiang ;
Chen, Wen ;
Yang, Fan .
ACS NANO, 2009, 3 (02) :478-482
[7]   Facile synthesis of α-MoO3 nanobelts and their pseudocapacitive behavior in an aqueous Li2SO4 solution [J].
Jiang, Jianbo ;
Liu, Jinlong ;
Peng, Sanjun ;
Qian, Dong ;
Luo, Dongming ;
Wang, Qunfeng ;
Tian, Ziwei ;
Liu, Youcai .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (07) :2588-2594
[8]   MCM-48-like large mesoporous silicas with tailored pore structure: Facile synthesis domain in a ternary triblock copolymer-butanol-water system [J].
Kim, TW ;
Kleitz, F ;
Paul, B ;
Ryoo, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (20) :7601-7610
[9]   ZnO@MoO3 core/shell nanocables: facile electrochemical synthesis and enhanced supercapacitor performances [J].
Li, Gao-Ren ;
Wang, Zi-Long ;
Zheng, Fu-Lin ;
Ou, Yan-Nan ;
Tong, Ye-Xiang .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (12) :4217-4221
[10]   MoO3 nanowires as electrochemical pseudocapacitor materials [J].
Liang, Renlong ;
Cao, Huaqiang ;
Qian, Dong .
CHEMICAL COMMUNICATIONS, 2011, 47 (37) :10305-10307