Syntheses of two imidazolate-4-amide-5-imidate linker-based hexagonal metal-organic frameworks with flexible ethoxy substituent

被引：27
作者：
Mondal, Suvendu Sekhar [1 ]
Dey, Subarna [2 ]
Baburin, Igor A. [3 ]
Kelling, Alexandra [1 ]
Schilde, Uwe [1 ]
Seifert, Gotthard [3 ]
Janiak, Christoph [2 ]
Holdt, Hans-Juergen [1 ]
机构：
[1] Univ Potsdam, Inst Chem, D-14476 Potsdam, Germany
[2] Univ Dusseldorf, Inst Anorgan Chem & Strukturchem, D-40204 Dusseldorf, Germany
[3] Tech Univ Dresden, Inst Phys Chem & Elektrochem, D-01062 Dresden, Germany
来源：
CRYSTENGCOMM | 2013年 / 15卷 / 45期
关键词：
CARBON-DIOXIDE; ADSORPTION; PRESSURE; LIGAND; ZINC;
D O I：
10.1039/c3ce41632a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A rare example of in situ linker generation with the formation of soft porous Zn- and Co-MOFs (IFP-9 and -10, respectively) is reported. The flexible ethoxy groups of IFP-9 and -10 protrude into the 1D hexagonal channels. The gas-sorption behavior of both materials for H-2, CO2 and CH4 showed wide hysteretic isotherms, typical for MOFs having a flexible substituent which can give rise to a gate effect.
引用
收藏
页码：9394 / 9399
页数：6
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