Syntheses of two imidazolate-4-amide-5-imidate linker-based hexagonal metal-organic frameworks with flexible ethoxy substituent

被引：27

作者：

Mondal, Suvendu Sekhar ^{[1
]}

Dey, Subarna ^{[2
]}

Baburin, Igor A. ^{[3
]}

Kelling, Alexandra ^{[1
]}

Schilde, Uwe ^{[1
]}

Seifert, Gotthard ^{[3
]}

Janiak, Christoph ^{[2
]}

Holdt, Hans-Juergen ^{[1
]}

机构：

[1] Univ Potsdam, Inst Chem, D-14476 Potsdam, Germany

[2] Univ Dusseldorf, Inst Anorgan Chem & Strukturchem, D-40204 Dusseldorf, Germany

[3] Tech Univ Dresden, Inst Phys Chem & Elektrochem, D-01062 Dresden, Germany

来源：

CRYSTENGCOMM | 2013年 / 15卷 / 45期

关键词：

CARBON-DIOXIDE; ADSORPTION; PRESSURE; LIGAND; ZINC;

D O I：

10.1039/c3ce41632a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rare example of in situ linker generation with the formation of soft porous Zn- and Co-MOFs (IFP-9 and -10, respectively) is reported. The flexible ethoxy groups of IFP-9 and -10 protrude into the 1D hexagonal channels. The gas-sorption behavior of both materials for H-2, CO2 and CH4 showed wide hysteretic isotherms, typical for MOFs having a flexible substituent which can give rise to a gate effect.

引用

页码：9394 / 9399

页数：6

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