Structure and reactivity of framework and extraframework iron in Fe-silicalite as investigated by spectroscopic and physicochemical methods

被引：636
作者：
Bordiga, S
Buzzoni, R
Geobaldo, F
Lamberti, C
Giamello, E
Zecchina, A
Leofanti, G
Petrini, G
Tozzola, G
Vlaic, G
机构：
[1] ENICHEM,CTR RECERCHE BOLLATE,I-20021 BOLLATE,MI,ITALY
[2] TRIESTE & SINCROTONE TRIESTE SCPA,DIPARTIMENTO SCI CHIM,I-34012 TRIESTE,ITALY
[3] IST NAZL FIS NUCL,I-10125 TURIN,ITALY
来源：
JOURNAL OF CATALYSIS | 1996年 / 158卷 / 02期
关键词：
D O I：
10.1006/jcat.1996.0048
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The application of LR, Raman, UV-visible, EPR, XANES, EXAFS, and TPR techniques to the determination of the Fe3+ local environment in Fe-silicalite is described and discussed. These methods give information concerning the structural changes of the zeolitic structure, upon thermal treatments and interaction with adsorbates. In particular the effect of template burning at 773 K or at 973 K on the local Fe3+ environment has been discussed in detail. The reactivity of the zeolite towards NH3 has also been considered. (C) 1996 Academic Press, Inc.
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收藏
页码：486 / 501
页数：16
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