Colorimetric detection of hydrogen peroxide by dioxido-vanadium(V) complex containing hydrazone ligand: synthesis and crystal structure

被引：7

作者：

Kurbah, Sunshine D. ^{[1
]}

Syiemlieh, Ibanphylla ^{[1
]}

Lal, Ram A. ^{[1
]}

机构：

[1] North Eastern Hill Univ, Dept Chem, Ctr Adv Studies, Shillong 793022, Meghalayn, India

来源：

ROYAL SOCIETY OPEN SCIENCE | 2018年 / 5卷 / 03期

关键词：

colorimetric; vanadium(V) complex; crystal structure; H2O2; DIOXIDOVANADIUM(V) COMPLEXES; DONOR LIGANDS; VANADIUM; OXIDATION; VANADATE; OLEFINS; SYSTEMS; ACID;

D O I：

10.1098/rsos.171471

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Dioxido-vanadium(V) complex has been synthesized in good yield, the complex was characterized by IR, UV visible and H-1 NM,R spectroscopy. Single crystal X-ray crystallography techniques were used to assign the structure of the complex. Complex crystallized with monoclinic P2(1)/c space group with cell parameters a (angstrom)= 39.516(5), b (angstrom)= 6.2571(11), c (angstrom) = 17.424(2), alpha (degrees) = 90, beta (degrees) =102.668(12) and gamma (degrees) = 90. The hydrazone ligand is coordinate to metal ion in tridentate fashion through ONO donor atoms forming a distorted square pyramidal geometry around the metal ion.

引用

页数：8

共 28 条

[21]

Plass W, 1999, ANGEW CHEM INT EDIT, V38, P909, DOI 10.1002/(SICI)1521-3773(19990401)38:7<909::AID-ANIE909>3.0.CO

[22]

2-S

[23] Biological and medicinal aspects of vanadium [J].

Rehder, D .

INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (05) :604-617

[24] The role of vanadium in biology [J].

Rehder, Dieter .

METALLOMICS, 2015, 7 (05) :730-742

[25] Oxovanadium(IV) and -(V) complexes of dithiocarbazate-based tridentate Schiff base ligands: Syntheses, structure, and photochemical reactivity of compounds involving imidazole derivatives as coligands [J].

Samanta, S ;

Ghosh, D ;

Mukhopadhyay, S ;

Endo, A ;

Weakley, TJR ;

Chaudhury, M .

INORGANIC CHEMISTRY, 2003, 42 (05) :1508-1517

[26]

Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S0108767307043930, 10.1107/S2053273314026370]

[27] Reduction of [VO2(ma)2]- and [VO2(ema)2]- by ascorbic acid and glutathione:: Kinetic studies of pro-drugs for the enhancement of insulin action [J].

Song, B ;

Aebischer, N ;

Orvig, C .

INORGANIC CHEMISTRY, 2002, 41 (06) :1357-1364

[28] Colorimetric detection of hydrogen peroxide and glucose using the magnetic mesoporous silica nanoparticles [J].

Wang, Yonghong ;

Zhou, Bo ;

Wu, Shun ;

Wang, Kemin ;

He, Xiaoxiao .

TALANTA, 2015, 134 :712-717

← 1 2 3 →