Colorimetric detection of hydrogen peroxide by dioxido-vanadium(V) complex containing hydrazone ligand: synthesis and crystal structure

被引：7

作者：

Kurbah, Sunshine D. ^{[1
]}

Syiemlieh, Ibanphylla ^{[1
]}

Lal, Ram A. ^{[1
]}

机构：

[1] North Eastern Hill Univ, Dept Chem, Ctr Adv Studies, Shillong 793022, Meghalayn, India

来源：

ROYAL SOCIETY OPEN SCIENCE | 2018年 / 5卷 / 03期

关键词：

colorimetric; vanadium(V) complex; crystal structure; H2O2; DIOXIDOVANADIUM(V) COMPLEXES; DONOR LIGANDS; VANADIUM; OXIDATION; VANADATE; OLEFINS; SYSTEMS; ACID;

D O I：

10.1098/rsos.171471

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Dioxido-vanadium(V) complex has been synthesized in good yield, the complex was characterized by IR, UV visible and H-1 NM,R spectroscopy. Single crystal X-ray crystallography techniques were used to assign the structure of the complex. Complex crystallized with monoclinic P2(1)/c space group with cell parameters a (angstrom)= 39.516(5), b (angstrom)= 6.2571(11), c (angstrom) = 17.424(2), alpha (degrees) = 90, beta (degrees) =102.668(12) and gamma (degrees) = 90. The hydrazone ligand is coordinate to metal ion in tridentate fashion through ONO donor atoms forming a distorted square pyramidal geometry around the metal ion.

引用

页数：8

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