Interaction Dependence and Similarity in Thermal Expansion of a Dimorphic 1D Hydrogen-Bonded Organic Complex

被引:49
作者
Bhattacharya, Suman [1 ]
Saha, Binoy K. [1 ]
机构
[1] Pondicherry Univ, Dept Chem, Pondicherry 605014, India
关键词
NEGATIVE LATTICE EXPANSION; POLYMORPHISM; TEMPERATURE; TRANSITION;
D O I
10.1021/cg4009174
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The thermal expansion trends for the two one-dimensional hydrogen-bonded 1:2 cocrystal polymorphs of 1,2,3,4-cyclobutanetetracarboxylic acid and trans-1,2-bis(4-pyridyl)ethylene have been studied. The expansion modes were found to be highly anisotropic but similar in these two forms. The mode of expansions along different directions is found to depend on the nature of the interactions and contacts that are present along those directions.
引用
收藏
页码:3299 / 3302
页数:4
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