Photocatalytic decomposition of tetrachloroethylene in the gas phase with titanium dioxide as catalyst

被引：6

作者：

Hegedus, M

Dombi, A

Kiricsi, I

机构：

[1] Univ Szeged, Dept Inorgan & Analyt Chem, H-6701 Szeged, Hungary

[2] Univ Szeged, Dept Appl & Environm Chem, H-6701 Szeged, Hungary

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 2001年 / 74卷 / 02期

基金：

匈牙利科学研究基金会;

关键词：

tetrachloroethylene; photocatalysis; titanium dioxide; adsorption;

D O I：

10.1023/A:1017968507589

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The gas phase photocatalytic destruction of tetrachloroethylene (PCE) was investigated by using an in situ photocatalytic reactor with FF-IR analysis in batch mode. The main products of PCE degradation are CO2 and COCl2, with trichloroacetylchloride as an intermediate. It was found that the rate of PCE degradation and the appearance of products in the gas phase are highly dependent on their adsorption properties on the surface of the catalyst, besides other reaction conditions, such as the intensity of irradiation and the composition of the reaction mixture.

引用

页码：209 / 215

页数：7

共 8 条

[1] Photocatalytic destruction of VOCs in the gas-phase using titanium dioxide [J].