A comparative study of the corrosion inhibition of low carbon steel in HCl solution by an imine compound and its cobalt complex

被引:58
作者
Keles, Hulya [1 ]
Emir, Duygu Melis [1 ]
Keles, Mustafa [1 ]
机构
[1] Osmaniye Korkut Ata Univ, Fac Arts & Sci, Dept Chem, TR-80000 Osmaniye, Turkey
关键词
Acid solutions; Carbon steel; EIS; Polarization; SEM; Acid inhibition; MILD-STEEL; SCHIFF-BASE; THEORETICAL EVALUATION; ACID; ADSORPTION; COPPER; ALUMINUM; SURFACE;
D O I
10.1016/j.corsci.2015.07.013
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The inhibition ability of an imine compound (PTM) and its cobalt complex (CoPTM) towards low carbon steel (LCS) corrosion in HCl solution was studied at various concentrations and temperatures using potentiodynamic polarization curves (Tafel), electrochemical impedance spectroscopy (EIS), scanning electron microscope (SEM), and energy-dispersive X-ray spectroscopy (EDS) methods. Electrochemical measurements showed that the inhibition efficiencies of both PTM and CoPTM depend on concentration, temperature, and immersion time. An adsorption mechanism for PTM and CoPTM on the LCS in 1 M HCl solution was proposed and discussed. Electrochemical results confirmed that the adsorption of CoPTM was stronger than PTM. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:19 / 31
页数:13
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