A Perspective on the Synthesis, Purification, and Characterization of Porous Organic Cages

被引：110

作者：

Briggs, Michael E. ^{[1
]}

Cooper, Andrew I. ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

CHEMISTRY OF MATERIALS | 2017年 / 29卷 / 01期

基金：

欧洲研究理事会;

关键词：

DYNAMIC COVALENT CHEMISTRY; ARYLENEETHYNYLENE CAGES; ALKYNE METATHESIS; MOLECULAR-SOLIDS; FLOW SYNTHESIS; SURFACE-AREA; POROSITY; DESIGN; SIMULATIONS; POLYHEDRA;

D O I：

10.1021/acs.chemmater.6b02903

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Porous organic cages present many opportunities in functional materials chemistry, but the synthetic challenges for these molecular solids are somewhat different from those faced in the areas of metal organic frameworks, covalent organic frameworks, or porous polymer networks. Here, we highlight the practical methods that we have developed for the design, synthesis, and characterization of imine porous organic cages using CC1 and CC3 as examples. The key points are transferable to other cages, and this perspective should serve as a practical guide to researchers who are new to this field.

引用

页码：149 / 157

页数：9

共 52 条

[21]

Hasell T, 2010, NAT CHEM, V2, P750, DOI [10.1038/nchem.739, 10.1038/NCHEM.739]

[22]

Holst JR, 2010, NAT CHEM, V2, P915, DOI [10.1038/NCHEM.873, 10.1038/nchem.873]

[23] In silico Design of Supramolecules from Their Precursors: Odd-Even Effects in Cage-Forming Reactions [J].

Jelfs, Kim E. ;

Eden, Edward G. B. ;

Culshaw, Jamie L. ;

Shakespeare, Stephen ;

Pyzer-Knapp, Edward O. ;

Thompson, Hugh P. G. ;

Bacsa, John ;

Day, Graeme M. ;

Adams, Dave J. ;

Cooper, Andrew I. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (25) :9307-9310

[24] Molecular simulations to understand and to design porous organic molecules [J].

Jelfs, Kim E. ;

Cooper, Andrew I. .

CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2013, 17 (01) :19-30

[25] Large Self-Assembled Chiral Organic Cages: Synthesis, Structure, and Shape Persistence [J].

Jelfs, Kim E. ;

Wu, Xiaofeng ;

Schmidtmann, Marc ;

Jones, James T. A. ;

Warren, John E. ;

Adams, Dave J. ;

Cooper, Andrew I. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (45) :10653-10656

[26] Functional porous composites by blending with solution-processable molecular pores [J].

Jiang, S. ;

Chen, L. ;

Briggs, M. E. ;

Hasell, T. ;

Cooper, A. I. .

CHEMICAL COMMUNICATIONS, 2016, 52 (42) :6895-6898

[27] Molecular Dynamics Simulations of Gas Selectivity in Amorphous Porous Molecular Solids [J].

Jiang, Shan ;

Jelfs, Kim E. ;

Holden, Daniel ;

Hasell, Tom ;

Chong, Samantha Y. ;

Haranczyk, Maciej ;

Trewin, Abbie ;

Cooper, Andrew I. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (47) :17818-17830

[28] Porous organic molecular solids by dynamic covalent scrambling [J].

Jiang, Shan ;

Jones, James T. A. ;

Hasell, Tom ;

Blythe, Charlotte E. ;

Adams, Dave J. ;

Trewin, Abbie ;

Cooper, Andrew I. .

NATURE COMMUNICATIONS, 2011, 2

[29] Dynamic Covalent Chemistry Approaches Toward Macrocycles, Molecular Cages, and Polymers [J].

Jin, Yinghua ;

Wang, Qi ;

Taynton, Philip ;

Zhang, Wei .

ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47 (05) :1575-1586

[30] Recent advances in dynamic covalent chemistry [J].

Jin, Yinghua ;

Yu, Chao ;

Denman, Ryan J. ;

Zhang, Wei .

CHEMICAL SOCIETY REVIEWS, 2013, 42 (16) :6634-6654

← 1 2 3 4 5 6 →