The Role of Platinum in Proton Exchange Membrane Fuel Cells Evaluation of platinum's unique properties for use in both the anode and cathode of a proton exchange membrane fuel cell

被引：270
|
作者：
Holton, Oliver T. [1 ]
Stevenson, Joseph W. [1 ]
机构：
[1] Johnson Matthey, Royston SG8 5HE, Herts, England
来源：
PLATINUM METALS REVIEW | 2013年 / 57卷 / 04期
关键词：
OXYGEN REDUCTION REACTION; BIMETALLIC SURFACES; REPULSIVE INTERACTIONS; PROMOTED SULFIDATION; GRAPHITE-ELECTRODES; HYDROGEN OXIDATION; SCIENTIFIC ASPECTS; TRANSITION-METALS; O-2; REDUCTION; PART I;
D O I：
10.1595/147106713X671222
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Proton exchange membrane fuel cells (PEMFCs) dominate the transportation fuel cell market and platinum (Pt) is the catalyst material used for both anode and cathode. This review sets out the fundamentals of activity, selectivity, stability and poisoning resistance which make Pt or its alloys the best available materials to use in this application. It is clear that Pt is the only element which can meet the requirements for performance while avoiding slow reaction kinetics, proton exchange membrane (PEM) system degradation due to hydrogen peroxide (H2O2) formation and catalyst degradation due to metal leaching. Some of the means by which the performance of Pt can be enhanced are also discussed.
引用
收藏
页码：259 / 271
页数：13
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