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The effect of preparation conditions of Pt/Al2O3 on its catalytic performance for the H2-SCR in the presence of oxygen
被引:18
|作者:
Yuan, Lei
[1
]
Zheng, Xiang
[2
]
Duan, Kaijiao
[1
]
Hu, Hao
[1
]
Wang, Jinggang
[1
]
Woo, Seong Ihl
[3
]
Liu, Zhiming
[1
]
机构:
[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
[2] Renmin Univ China, Sch Environm & Nat Resources, Beijing 100872, Peoples R China
[3] Korea Adv Inst Sci & Technol, Grad Sch EEWS WCU, Dept Chem & Biomol Engn, Taejon 305701, South Korea
基金:
中国国家自然科学基金;
关键词:
NOx reduction;
Pt/Al2O3;
preparation condition;
H-2-SCR;
PT/MGO-CEO2;
CATALYST;
SELECTIVE REDUCTION;
EXCESS OXYGEN;
NITRIC-OXIDE;
NO;
HYDROGEN;
PROPENE;
SCR;
LEAN-DENO(X);
H-2;
D O I:
10.1007/s11783-013-0512-5
中图分类号:
X [环境科学、安全科学];
学科分类号:
08 ;
0830 ;
摘要:
Selective catalytic reduction of NO (x) by H-2 in the presence of oxygen has been investigated over Pt/ Al2O3 catalysts pre-treated under different conditions. Catalyst preparation conditions exert significant influence on the catalytic performance, and the catalyst pre-treated by H-2 or H-2 then followed by O-2 is much more active than that pre-treated by air. The higher surface area and the presence of metallic Pt over Pt/Al2O3 pre-treated by H-2 or pretreated by H-2 then followed by O-2 can contribute to the formation of NO2, which then promotes the reaction to proceed at low temperatures.
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页码:457 / 463
页数:7
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