The effect of preparation conditions of Pt/Al2O3 on its catalytic performance for the H2-SCR in the presence of oxygen

被引:18
|
作者
Yuan, Lei [1 ]
Zheng, Xiang [2 ]
Duan, Kaijiao [1 ]
Hu, Hao [1 ]
Wang, Jinggang [1 ]
Woo, Seong Ihl [3 ]
Liu, Zhiming [1 ]
机构
[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
[2] Renmin Univ China, Sch Environm & Nat Resources, Beijing 100872, Peoples R China
[3] Korea Adv Inst Sci & Technol, Grad Sch EEWS WCU, Dept Chem & Biomol Engn, Taejon 305701, South Korea
基金
中国国家自然科学基金;
关键词
NOx reduction; Pt/Al2O3; preparation condition; H-2-SCR; PT/MGO-CEO2; CATALYST; SELECTIVE REDUCTION; EXCESS OXYGEN; NITRIC-OXIDE; NO; HYDROGEN; PROPENE; SCR; LEAN-DENO(X); H-2;
D O I
10.1007/s11783-013-0512-5
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Selective catalytic reduction of NO (x) by H-2 in the presence of oxygen has been investigated over Pt/ Al2O3 catalysts pre-treated under different conditions. Catalyst preparation conditions exert significant influence on the catalytic performance, and the catalyst pre-treated by H-2 or H-2 then followed by O-2 is much more active than that pre-treated by air. The higher surface area and the presence of metallic Pt over Pt/Al2O3 pre-treated by H-2 or pretreated by H-2 then followed by O-2 can contribute to the formation of NO2, which then promotes the reaction to proceed at low temperatures.
引用
收藏
页码:457 / 463
页数:7
相关论文
共 50 条
  • [21] Effect of preparation conditions on the stability of Pt/Al2O3 catalysts in methane combustion
    Khelifi, L
    Ghorbel, A
    JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2000, 19 (1-3) : 643 - 646
  • [22] Insight into the Promotion Effect of Trace Pd Doping on the Catalytic Performance of Ag/Al2O3 for C3H6-SCR of NO x
    Liu, Zhi
    An, Yingsheng
    Xu, Guangyan
    Yu, Yunbo
    He, Hong
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2023, 57 (39) : 14760 - 14767
  • [23] Influence of Preparation Methods of In2O3/Al2O3 Catalyst on Selective Catalytic Reduction of NO by Propene in the Presence of Oxygen
    Junhua Li
    Jiming Hao
    Xiangyu Cui
    Lixin Fu
    Catalysis Letters, 2005, 103 : 75 - 82
  • [24] Effect of the modification of alumina supports with chloride on the structure and catalytic performance of Ag/Al2O3 catalysts for the selective catalytic reduction of NOx with propene and H2/propene
    Wang, Jia
    You, Rui
    Qian, Kun
    Pan, Yang
    Yang, Jiuzhong
    Huang, Weixin
    CHINESE JOURNAL OF CATALYSIS, 2021, 42 (12) : 2242 - 2253
  • [25] Improved NOx Reduction Using C3H8 and H2 with Ag/Al2O3 Catalysts Promoted with Pt and WOx
    Gonzalez Hernandez, Naomi N.
    Contreras, Jose Luis
    Pinto, Marcos
    Zeifert, Beatriz
    Flores Moreno, Jorge L.
    Fuentes, Gustavo A.
    Hernandez-Teran, Maria E.
    Vazquez, Tamara
    Salmones, Jose
    Jurado, Jose M.
    CATALYSTS, 2020, 10 (10) : 1 - 22
  • [26] Evolution of sulfate during the preparation of Pd/Al2O3 catalyst and its effect on the performance of catalytic hydrogenation
    Zhang, Zhe
    Xiao, Weiting
    He, Yufei
    Li, Dianqing
    Zhao, Xiaodong
    APPLIED CATALYSIS O: OPEN, 2024, 190
  • [27] Enhancement by H2 of C3H8-SCR of NOx using Ag/γ-Al2O3
    Hernandez-Teran, Maria E.
    Fuentes, Gustavo A.
    FUEL, 2014, 138 : 91 - 97
  • [28] Effect of preparation methods on the performance of CeO2/Al2O3 catalysts for selective catalytic reduction of NO with NH3
    Guo, Rui-tang
    Zhou, Yue
    Pan, Wei-guo
    Hong, Jie-nan
    Zhen, Wen-long
    Jin, Qiang
    Ding, Cheng-gang
    Guo, Shi-yi
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2013, 19 (06) : 2022 - 2025
  • [29] Study of the "Fast SCR"-like mechanism of H2-assisted SCR of NOx with ammonia over Ag/Al2O3
    Doronkin, Dmitry E.
    Fogel, Sebastian
    Tamm, Stefanie
    Olsson, Louise
    Khan, Tuhin Suvra
    Bligaard, Thomas
    Gabrielsson, Par
    Dahl, Soren
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2012, 113 : 228 - 236
  • [30] Comparison of dual CO light-off effect on Pt/CeO2/γ-Al2O3, Pd/CeO2/γ-Al2O3, Pt/c-Al2O3 and Pd/γ-Al2O3 in the presence of C3H6
    Brezina, Jan
    Pecinka, Rudolf
    Boutikos, Panagiotis
    Koci, Petr
    CHEMICAL ENGINEERING SCIENCE, 2020, 218 (218)