Optical, physical and structural studies of vanadium doped P2O5-BaO-Li2O glasses

Glasses in the compositions (Li2O)(25)-(BaO)(25)-(P2O5)(50-x)-(V2O5)(x) (with x=0.5,1.0,1.5,2.0,2.5, and 3.0 mol %) have been prepared by the conventional melt quenching technique. X-ray powder diffractrogram show broad peaks which conforms glassy nature of the sample. Differential scanning calorimetry (DSC) thermograms show characteristic glass transition temperature (T-g) and it increases with increasing substitution of V2O5 for P2O5. The measured physical parameters like density, refractive index, ionic concentration and electronic polarizability are found to vary linearly with increasing x. Infrared spectra exhibits few bands, which are attributed to (P=O)(AS,) (P=O)(S), (V=O), (P-O-P)(AS),P-O-V, (P-O-P)(AS) and O-P-O vibrations. The optical absorption spectra of VO2+ ions in these glasses show three bands and are assigned to the B-2(2 ->) E-2,B-2(2 ->) B-2(1) and B-2(2)-> (2)A(1) transitions. Electron paramagnetic resonance spectra of all the glass samples exhibit resonance signals characteristic of VO2+ ions. The values of Spin-Hamiltonian parameters indicate that the VO2+ ions are present in octahedral sites with tetragonal compression and belong to C-4V symmetry. (C) 2013 Elsevier Ltd. All rights reserved.