Molecular Structure of a Cyclopropyl Substituted Vinyl Cation

被引：24

作者：

Klaer, Andrea ^{[1
]}

Saak, Wolfgang ^{[1
]}

Haase, Detlev ^{[1
]}

Mueller, Thomas ^{[1
]}

机构：

[1] Carl von Ossietzky Univ Oldenburg, Inst Pure & Appl Chem, D-26211 Oldenburg, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 45期

关键词：

D O I：

10.1021/ja8069055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The experimentally determined molecular structure of vinyl cation 1 provides clear evidence for the occurrence of extended a-conjugation involving the cyclopropyl ring and the beta-C-Si bonds.

引用

页码：14956 / +

页数：3

共 23 条

[1]

Anslyn E. V., 2006, MODERN PHYS ORGANIC

[2] THE STRUCTURE OF CYCLOPROPYLCARBINYL CATIONS - THE CRYSTAL-STRUCTURES OF PROTONATED CYCLOPROPYL KETONES [J].

CHILDS, RF ;

KOSTYK, MD ;

LOCK, CJL ;

MAHENDRAN, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (24) :8912-8920

[3] STRUCTURES OF 2 CYCLOPROPYLCARBINYL CATIONS [J].

CHILDS, RF ;

FAGGIANI, R ;

LOCK, CJL ;

MAHENDRAN, M ;

ZWEEP, SD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (07) :1692-1693

[4]

Frisch M.J., 2004, Gaussian 03

[5]

Revision C.02

[6] Comparison of carbon-silicon hyperconjugation at the 2-and 4-positions of the N-methylpyridinium cation [J].

Hassall, K ;

Lobachevsky, S ;

White, JM .

JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (06) :1993-1997

[7] Carbon-silicon hyperconjugation and strain-enhanced hyperconjugation:: Structures of N-methyl 2-and 4-tert-butyldimethylsilylmethyl pyridinium cations [J].

Hassall, Kathryn ;

Lobachevsky, Sofia ;

Schiesser, Carl H. ;

White, Jonathan M. .

ORGANOMETALLICS, 2007, 26 (06) :1361-1364

[8] Solution and x-ray structure of triethylsilylmethyl-substituted tropylium cation [J].

Hassall, KS ;

White, JM .

ORGANIC LETTERS, 2004, 6 (11) :1737-1739

[9] HIGH-RESOLUTION RAMAN SPECTROSCOPY OF GASES .18 . PURE ROTATIONAL SPECTRA OF CYCLOPROPANE + CYCLOPROPANE-D61 [J].

JONES, WJ ;

STOICHEFF, BP .

CANADIAN JOURNAL OF PHYSICS, 1964, 42 (11) :2259-&

[10] MOLECULAR-STRUCTURE OF CYCLOPROPYLACETYLENE AS STUDIED BY GAS ELECTRON-DIFFRACTION [J].

KLEIN, AW ;

SCHRUMPF, G .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1981, 35 (06) :431-435

← 1 2 3 →