Construction of two new cadmium(II) coordination polymers based on dicarboxylate and 4,4-bis(1-imidazol-yl)-2,5-dimethyl benzene ligands

被引：41
作者：
Xu, Guilan [1 ]
Guo, Feng [1 ]
机构：
[1] Dezhou Univ, Key Lab Coordinat Chem & Funct Mat Univ Shandong, Dezhou 253023, Shandong, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 27卷
关键词：
Crystal structure; Cadmium; Topology; ORGANIC FRAMEWORKS; NETWORK; CD(II); COLIGANDS; CLUSTERS; ZEOLITE; CO2; NI;
D O I：
10.1016/j.inoche.2012.10.025
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new Cd(II) coordination polymersnamely [Cd-2(ipa)(2)(bib)(1.5)](n) (1; H(2)ipa = isophthalic acid and bib = 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene) and {[Cd-2(bpdc)(2)(bib)(2)]center dot 5H(2)O}(n) (2; H(2)bpdc = biphenyl-4,4'-dicarboxylate), were prepared by the assemble of Cd2+, dicarboxylate and bib ligands. Complex 1 shows a three-dimensional (3D) framework with 7-connected topological net, which can be viewed as constructing by linking two-fold interpenetrating pcu net. Complex 2 features a 3D 2-fold pcu topological net. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：146 / 148
页数：3
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