Azocalix[4]arene Strapped Calix[4]pyrrole: A Confirmable Fluoride Sensor

被引：60

作者：

Thiampanya, Preecha

Muangsin, Nongnuj

Pulpoka, Buncha ^{[1
]}

机构：

[1] Chulalongkorn Univ, Supramol Chem Res Unit, Dept Chem, Fac Sci, Bangkok 10330, Thailand

来源：

ORGANIC LETTERS | 2012年 / 14卷 / 16期

关键词：

ION-PAIR RECEPTOR; ANIONS; RECOGNITION; CHEMOSENSOR; HYDROGEN; PROBE;

D O I：

10.1021/ol301684r

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new chromogenic fluoride sensor based on 1,3-di-p-nitrophenylazocalix[4]arene-calix[4]pyrrole (1) was designed and synthesized. The color of the solution of probe 1 changed upon the addition of any F-, CH3CO2-, PhCO2-, and H2PO4- ions. However, from these ions the highly specific sensing of F- is achieved by the addition of Ca2+ which leads to a color change from light sky blue (of 1.F-) back to the original light orange color of 1.

引用

收藏

页码：4050 / 4053

页数：4

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[1] A Bifunctional Chromogenic Calix[4]arene Chemosensor for Both Cations and Anions: A Potential Ca2+ and F- Switched INHIBIT Logic Gate with a YES Logic Function [J].

Chang, Kai-Chi ;

Su, In-Hao ;

Wang, Yu-Yun ;

Chung, Wen-Sheng .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 2010 (24) :4700-4704

[2] Azocalix[4]arene-based chromogenic anion probes [J].

Chen, CF ;

Chen, QY .

NEW JOURNAL OF CHEMISTRY, 2006, 30 (02) :143-147

[3] NEW CHROMOIONOPHORES [J].

DIX, JP ;

VOGTLE, F .

CHEMISCHE BERICHTE-RECUEIL, 1981, 114 (02) :638-651

[4] Synthesis of new calix[4]pyrrole derivatives via 1,3-dipolar cycloadditions [J].

Farinha, Andreia S. F. ;

Tome, Augusto C. ;

Cavaleiro, Jose A. S. .

TETRAHEDRON, 2010, 66 (38) :7595-7599

[5] Fluoride Ion Sensing by an Anion-π Interaction [J].

Guha, Samit ;

Saha, Sourav .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (50) :17674-17677

[6] Anion recognition and sensing in organic and aqueous media using luminescent and colorimetric sensors [J].

Gunnlaugsson, Thorfinnur ;

Glynn, Mark ;

Tocci , Gillian M. ;

Kruger, Paul E. ;

Pfeffer, Frederick M. .

COORDINATION CHEMISTRY REVIEWS, 2006, 250 (23-24) :3094-3117

[7] A Highly Selective Bifunctional Luminescence Probe for Potassium and Fluoride Ions [J].

He, Xiaoming ;

Yam, Vivian Wing-Wah .

ORGANIC LETTERS, 2011, 13 (09) :2172-2175

[8] A new fluorescent chemosensor for F- based on inhibition of excited-state intramolecular proton transfer [J].

Jung, Hyci Sung ;

Kim, Hyun Jung ;

Vicens, Jacques ;

Kim, Jong Seung .

TETRAHEDRON LETTERS, 2009, 50 (09) :983-987

[9] A reversible Em-FRET rhodamine-based chemosensor for carboxylate anions using a ditopic receptor strategy [J].

Kaewtong, Chatthai ;

Noiseephum, Jakkapong ;

Uppa, Yuwapon ;

Morakot, Nongnit ;

Morakot, Neramit ;

Wanno, Banchob ;

Tuntulani, Thawatchai ;

Pulpoka, Buncha .

NEW JOURNAL OF CHEMISTRY, 2010, 34 (06) :1104-1108

[10] Ester and Ketone Groups Substituted Mono- and Di- Azo-coupled Azocalix[4]arenes as Extractant for Hg+ and Hg2+, or Cr3+Cations [J].

Karakus, Ozlem Ozen ;

Deligoz, Hasalettin .

JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2010, 47 (11) :1111-1115