Benzotriazole as a volatile corrosion inhibitor during the early stage of copper corrosion under adsorbed thin electrolyte layers

被引：144
|
作者：
Chen, Zhenyu [1 ]
Huang, Ling [1 ]
Zhang, Guoan [1 ]
Qiu, Yubing [1 ]
Guo, Xingpeng [1 ]
机构：
[1] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Peoples R China
来源：
CORROSION SCIENCE | 2012年 / 65卷
基金：
中国国家自然科学基金;
关键词：
Copper; AFM; EIS; XPS; Neutral inhibition; Atmospheric corrosion; SELF-ASSEMBLED MONOLAYERS; ATMOSPHERIC CORROSION; SURFACE; BEHAVIOR; STEEL; FILMS; ADSORPTION; PROTECTION; XPS; SPECTROSCOPY;
D O I：
10.1016/j.corsci.2012.08.019
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The inhibition effect of benzotriazole (BTAH) during the early stage of copper corrosion under adsorbed thin electrolyte layers (ATEL) was investigated. Electrochemical data show that BTAH suppressed the anodic corrosion reaction and inhibited copper corrosion under ATEL. The surface was examined by using a scanning electron microscopy, in situ atomic force microscopy, X-ray photoelectron spectroscopy, and attenuated total reflectance Fourier-transform infrared measurements. The inhibition of BTAH is attributed to its quick interaction with Cu(0) that formed a thin protective film in non-corroded areas and interaction with Cu(I) that formed a complex on Cu2O substrate in defect sites. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：214 / 222
页数：9
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