Grignard metathesis (GRIM) polymerization for the synthesis of conjugated block copolymers containing regioregular poly(3-hexylthiophene)

被引:108
|
作者
Stefan, Mihaela C. [1 ]
Bhatt, Mahesh P. [1 ]
Sista, Prakash [1 ]
Magurudeniya, Harsha D. [1 ]
机构
[1] Univ Texas Dallas, Dept Chem, Richardson, TX 75080 USA
基金
美国国家科学基金会;
关键词
CATALYST-TRANSFER POLYCONDENSATION; ROD-COIL; ELECTRICAL-CONDUCTIVITY; MOLECULAR-WEIGHT; FACILE SYNTHESIS; POLYTHIOPHENE; DIBLOCK; POLY(3-ALKYLTHIOPHENES); MORPHOLOGIES; THIOPHENE);
D O I
10.1039/c1py00453k
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synthesis of various conjugated block copolymers of regioregular poly(3-hexylthiophene) by Grignard metathesis (GRIM) polymerization is described.
引用
收藏
页码:1693 / 1701
页数:9
相关论文
共 50 条
  • [1] Synthesis of Di-block Copolymers Containing Regioregular Poly(3-hexylthiophene) and Poly(tetrahydrofuran) by a Combination of Grignard Metathesis and Cationic Polymerizations
    Alemseghed, Mussie G.
    Gowrisanker, Srinivas
    Servello, John
    Stefan, Mihaela C.
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2009, 210 (23) : 2007 - 2014
  • [2] Role of the transition metal in Grignard metathesis polymerization (GRIM) of 3-hexylthiophene
    Bhatt, Mahesh P.
    Magurudeniya, Harsha D.
    Sista, Prakash
    Sheina, Elena E.
    Jeffries-EL, Malika
    Janesko, Benjamin G.
    McCullough, Richard D.
    Stefan, Mihaela C.
    JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (41) : 12841 - 12849
  • [3] Influence of reaction time on properties of regioregular poly(3-hexylthiophene) by the Grignard metathesis polymerization
    Mota, Isabela Custodio
    Silva Santos, Bianca Pedroso
    Pereira dos Santos, Raphael Ertola
    Guedes, Luisa Banar
    Soares, Igor Tenorio
    Rubio Arias, Jose Jonathan
    de Araujo, Francineide Lopes
    Nogueira, Ana Flavia
    Vieira Marques, Maria de Fatima
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2022, 147 (08) : 5037 - 5048
  • [4] Amphiphilic Block Copolymers Containing Regioregular Poly(3-hexylthiophene) and Poly(2-ethyl-2-oxazoline)
    Alemseghed, Mussie G.
    Servello, John
    Hundt, Nadia
    Sista, Prakash
    Biewer, Michael C.
    Stefan, Mihaela C.
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2010, 211 (12) : 1291 - 1297
  • [5] Synthesis and crystallization behavior of regioregular-block-regiorandom poly(3-hexylthiophene) copolymers
    Kim, Jin-Seong
    Choi, Jee-Eun
    Park, Hyeonjung
    Kim, Youngkwon
    Kim, Hyeong Jun
    Han, Junghun
    Shin, Jae Man
    Kim, Bumjoon J.
    POLYMER CHEMISTRY, 2019, 10 (23) : 3030 - 3039
  • [6] Thermally Induced Coupling of Poly(thiophene)-Based Block Copolymers Prepared by Grignard Metathesis Polymerization: A Straightforward Route toward Highly Regioregular Multiblock Conjugated Copolymers
    Ouhib, Farid
    Desbief, Simon
    Lazzaroni, Roberto
    De Winter, Julien
    Gerbaux, Pascal
    Jerome, Christine
    Detrembleur, Christophe
    MACROMOLECULES, 2012, 45 (17) : 6796 - 6806
  • [7] Regioregular poly(3-hexylthiophene)-poly(ε-caprolactone) block copolymers: Controlled synthesis, microscopic morphology, and charge transport properties
    Surin, Mathieu
    Coulembier, Olivier
    Tran, Khoa
    De Winter, Julien
    Leclere, Philippe
    Gerbaux, Pascal
    Lazzaroni, Roberto
    Dubois, Philippe
    ORGANIC ELECTRONICS, 2010, 11 (05) : 767 - 774
  • [8] Synthesis, mobility, and conductivity of well-defined regioregular poly(3-hexylthiophene) and diblock copolymers of regioregular poly(3-hexylthiophene)
    Sauve, Genevive
    Zhang, Rui
    Jia, Shijun
    Kowalewski, Tomasz
    McCullough, Richard D.
    ORGANIC FIELD-EFFECT TRANSISTORS V, 2006, 6336
  • [9] Novel regioregular poly(3-hexylthiophene)-based polycationic block copolymers
    Ha Tran Nguyen
    Coulembier, Olivier
    De Winter, Julien
    Gerbaux, Pascal
    Crispin, Xavier
    Dubois, Philippe
    POLYMER BULLETIN, 2011, 66 (01) : 51 - 64
  • [10] Synthesis and Characterization of a Block Copolymer Containing Regioregular Poly(3-hexylthiophene) and Poly(γ-benzyl-L-glutamate)
    Hundt, Nadia
    Quan Hoang
    Hien Nguyen
    Sista, Prakash
    Hao, Jing
    Servello, John
    Palaniappan, Kumaranand
    Alemseghed, Mussie
    Biewer, Michael C.
    Stefan, Mihaela C.
    MACROMOLECULAR RAPID COMMUNICATIONS, 2011, 32 (03) : 302 - 308