Features of Reactions of Radical (Co)Polymerization of Methacryloylguanidine Trifluoroacetate in Various Solvents

被引：2

作者：

Menyashev, M. R. ^{[1
]}

Gerasin, V. A. ^{[1
]}

Martynenko, A. I. ^{[1
]}

Kleshcheva, N. A. ^{[1
]}

Popova, N. I. ^{[1
]}

Sivov, N. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Topchiev Inst Petrochem Synth, Moscow 119991, Russia

来源：

POLYMER SCIENCE SERIES B | 2017年 / 59卷 / 06期

关键词：

NANOCOMPOSITES; METHACRYLATE;

D O I：

10.1134/S1560090417060057

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A method for the synthesis of methacryloylguanidine trifluoroacetate was developed for the first time and its radical (co)polymerization was carried out in various solvents. The polymerization proceeds homogeneously in water, methanol, and DMSO up to high conversion and heterogeneously in acetone after reaching 20% conversion. For the first time, methacryloylguanidine trifluoroacetate and methylmethacrylate copolymers were synthesized in acetone and DMSO; the copolymerization constants for this system in acetone were determined to be r(1) = 1.41 perpendicular to 0.24 and r(2) = 0.11 perpendicular to 0.01. Preliminary biological tests showed a fairly high biocidal and fungicidal activity of the synthesized copolymers.

引用

页码：650 / 654

页数：5

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